聚酰亚胺_氧化硅_氧化铝纳米复合薄膜的制备及性能研究.pdfVIP

2005 No. 1 : / / 9 / / 张晶波, 范 勇, 衷敬和, 王 芳 ( , 150040) : N, N , SiO2 Al2O3 , , , : ; ; ; ; : T M 2 15. 3; T Q323. 7; T Q 316. 62 : A : 1009- 9239( 2005) 01- 0009- 04 Study on the preparation and properties of pol yimide/ si lica/ al umi na nano_composite fi lm ZHANG Jing_bo, FAN Yong, ZHONG j ing_he, WANG Fang (T he Col leg e of M ate r i al S cie nce E ng in eer ing , H ar bin Un iv . S ci ., H ar bin 150040, Chi n a ) Abstract : In thi a er, b the Sol_Gel roce of TEOS, MTEOS and hetero ro l_aluminium in p p y p p py PAA(DMAC) olution, Pol imide com o ite film with an amount of SiO and Al O are re ared. y p 2 2 3 p p The urface morphology and chemical tructure of the film are characterized by Atomic Force Micro cope (AFM) and Fourier Tran form Infrared Spectro cope(FTIR) . And the propertie uch a thermal tabilit and electric ro ert with inor anic content and the mor holo between the y p p y g p gy or anic and inor anic ha e are di cu ed. It i turned out that the SiO and Al O article are g g p 2 2 3 p finely di per ed in the polyimide membrane ample . It i howed by the experiment that incor porating inorganic moiety into polymer re in and the character of interface between the two ha e ha reat effect on the ro ertie of the h brid film com ared with tho e of the ure p g p p y p p ol imide. p y Ke words: ol imide film; ilica; alumina; nano_com o ite; ol_ el y p y