H13钢表面电火花改性及其耐蚀性能研究.pdf

H13 , , , , (太原理工大学 表面工程研究所, 山西 太原 030024) : , H 13, ( GDOES) X , , , , T i; H 13, 06mol/LN aC l - 371 mV, - 472 mV ; 0 m ol/L : ; H 13; ; : TG17444; TG1725 :A : 0254-6051(2008)08-0044-03 Study on surface odification ofH13 steelby electric spark deposition and its corrosion resistance WANG Yao-wu, FENG Hong, WANG He-feng, Q IN L in, TANG Bin ( Research Institute of Surface Engineering, T aiyuan Un iversity of Technology, Taiyuan Shanxi 030024, Ch ina) Abstract:T itan ium modified layer w as fabricated by electric spark deposition techn iqueW ith metalloscope, G low D is- charge Optical Em ission Spectroscopy( GDOES) and X-ray diffraction measurem ents, the mod ified layerw as character- izedThe electrochem istry behavior of titan ium modified layerw as investigatedThe resu lts show that an un iform and con- tinuous titanium modified layer is formed on the surface ofH 13 steel basew ith ametallurgical bonded to the substrateT i element in the mod ified layer show s grad ient d istributionCompared w ith H 13 base, the free corrosion potential of the modified layer in 06mol/L NaCl solution( - 371 mV ) is higher than that ofH 13 base( - 472 mV ). Correspond ingly, the corrosion resistance of the modified layer is obviously mi proved in 0 mol/L su lfuric acid solution. Keywords: electric spark deposition; H 13 steel; titan ium mod ified layer; corrosion resistance , , , [ 4] , () H 13 (), , 06 , , mol/L NaC l 0 mol/L H SO 2 4 ; [ 1] , 1 试验材料与方法 H 13, , [ 2-3] 30 mm 30 mm mm , 100