过渡金属敏化稀土化合物近红外发光性能研究进展.pdfVIP

19 6 ( ) Vol. 19 No. 6 2007 12 Journal of Chongqing University of Posts an Telecommunications(Natural Science) Dec.2007 * 周贤菊, 赵 亮, 罗 斌 ( , 400065) : 稀土元素由于具有特殊的电子构型而使得稀土原子或离子的化合物( 合物) 有很多独特的物理和化学性 质, 尤其是稀土化合物的发光性能, 但由于跃迁选择定则, 稀土化合物的发光性能比较弱, 需要用过渡金属离子对 稀土化合物进行敏化, 以增强其发光性能在这 个过程中, 过渡金属离子的最低激发态不直接参与发光的辐射跃 迁, 却可以改善稀土化合物的发光性能围绕过渡金属敏化稀土化合物发光的研究方法研究成果以及其发展前 景进行了综述 : 过渡金属; 敏化; 稀土化合物; 近红外; 发光 : O 18 : A : 1673- 825X( 2007) 06-0771-04 Progress in research of transition-metal sensitize near-infrare luminescence for rare-earth compoun s ZHOU Xian-ju, ZHAO Liang, LU O Bin ( C llege f Electr nic Engin eering, Ch ngqing University f P sts and Telec m municati ns, Ch ngqing 400065, P. R. China) Abstract: Rare-earth c mp unds are f s me unique phy sical and chemical pr perties because f their special elec- tr nic c nfigurati ns, especially its luminescent pr perties. H w ever, lum inescence fr m rare-earth i ns is rather weak acc rding t transfer selecti n rules. T enhance their luminescence, it is necessary t sensitize the rare-earth i ns w ith transiti n-met al i ns. In this pr cess, the l w est excited states f transit i n-metal i ns can impr ve the lu- minescent pr perties th ugh they d n t w rk in the emissi n transfer f luminescence directly . This paper c ncen- trates n research meth ds and achievements as well as the future f the transiti n-metal sensit ized luminescence f rare-earth c mp unds. Key wor s:t ransiti n-metal; sensitizing; rare-earth c mp unds; near-infrared; luminescence , 0 , , , ( near-infr ar ed) ASTM ,