低截留分子量PPES超滤膜的制备.pdfVIP

Vol. 21 No. 3 2008 9 Journal of Functional Polymer s 317 PPES 高 嵩, 张守海, 杨大令, 孙 杨, 蹇锡高 ( 大连理工大学化工学院, 辽宁省高性能树脂工程技术研究中心, 辽宁大连 11 012) : 杂萘联苯聚醚砜( PPES) 为膜材料N 甲基吡咯烷酮( NMP) 为溶剂有机小分子丙醇 ( PrOH) 和无机小分子氯化锂( LiCl) 作为混合添加剂, 采用相转化法制备超滤膜研究了聚合物浓 度混合添加剂配比凝胶浴温度等对膜结构和性能的影响结果表明: 随聚合物浓度的增大, 膜的 纯水通量下降, 截留率升高; 混合添加剂, 在 PrOH 含量为12% LiCl 含量为1. 5% 时, 可制得纯水 2 通量为252 L/ ( m !h) , 对聚乙二醇1000( PEG1000) 截留率为9 %的超滤膜; 随凝胶浴温度的升 高, 膜的纯水通量增加 : 杂萘联苯聚醚砜; 低截留分子质量; 超滤膜 : TQ028. 8 : A : 2008) Preparation of Poly( Phthalazinone Ether Sulfone) Ultrafiltration Membrane with Low Molecular Weight CutOff GAO Song, ZHANG Shouhai, YANG Daling, SU N Yang, JIAN Xigao ( Liaoning Research Center of H ighPerformance Resin Engineering and Technology, College of Chemical Engineering, Dalian U niversity of Technology, Dalian 11 012, Liaoning, China) Ab tract: By using poly( phthalazinone ether sulfone) ( PPES) as membrane material, NMP as solvent and organic substance PrOH and inorganic substance LiCl mixture as additive, the ultrafiltration mem branes w ere prepared w ith a phase inversion technique. Effects of the polymer concentration, the content of Pr OH and LiCl in additive and gelbath temperature on membrane∀s structure and performance w ere studied. Results show that w ater fluxes of the membrane decrease w ith the increasing of polymer concen tration, w hile the rejection rate increase. With the content of PrOH 12% , LiCl 1. 5% as additive, the 2 membrane w ith high w ater flux 252 L/ ( m ! h) and high PEG1000 rejection rate 9 % is prepared. The w ater fluxes of the membrane also increase w ith the increasing of gelbath temperature. Key word : PPES; low molecular w eight cut