机械研磨法制备石墨烯调研.ppt

机械研磨法调研 张阳 2011.09.22 * 文献：“Patterning of highly oriented pyrolytic graphite by oxygen plasma etching” （1999） 关键词：HOPG SiO2 光刻胶 HF酸 石墨柱 FIG.1.SEM images of island arrays created on a HOPG surface FIG.2.SEM images HOPG islands smeared on a Si(001) substrate 厚度小于10个纳米 文献：“Fabrication and electric-field-dependent transport measurements?of ?mesoscopic graphite devices”（2005） 关键词：氧离子刻蚀 HOPG AFM FIG .3.thicknesses ranging from 10 to 100 nm and lateral size ,2 um 文献：“Electric Field Effect in Atomically Thin Carbon Films” （2004） FIG.4.不同厚度的石墨烯片层在光学显微镜下的照片 所标厚度为AFM测量值 FIG.5.有褶皱的单层石墨烯AFM图 KEY WORD: patterning HOPG photoresist scotch tape peeling acetone SI/SIO2 water propanol ultrasound RESULT: d10 nm flake 文献：“Low energy pure shear milling: A method for the preparation of graphite nano-sheets”（2006） KEY WORD: graphite powder bowl pestle water (001) lattice plane FIG.6.SEM micrographs of (a) graphite powder ,(b) and (c) graphite milled 20h Table.1.The specific surface area of the powders, Sbet; the average thick 文献：“Preparation of Colloidal Dispersions of Graphene Sheets in Organic Solvents by Using Ball Milling”（2010） FIG.7.(a)GNs dispersed in solvent are delaminated by mill balls in grinding process (b) graphene sheets are formed in situ in solvent FIG.8. AFM image of the supernatant graphene deposited on a mica substrate 文献：“Preparation and examination of multilayer graphene nanosheets by exfoliation of graphite in high efficient attritor mill”(2010) FIG.9.(a) high efficient attritor mill FIG.10.(b) 酒精溶剂中研磨10h的SEM图片，多层石墨烯层完全分开了 文献：“Depositing graphene films on solid and perforated substrates” FIG.11.Schematic con?guration of the ‘writing tool’: the substrate is put on a 2D stage. The HOPG ingot is gently touching the substrate and the stage is moved to obtain the desired printed feature。 FIG.12.transparent 2D crystal on top of the Si 石墨晶体中相邻两层石墨烯之间的范德华作用约为2evnm-2 Typical experimental conditions were: oxygen