Rheology+Characterization+of+PET／E-HDP+Blending+System.pdfVIP

维普资讯 第 2O卷第 2期 青 岛大 学 学 报 (工 程 技 术 版 ) Vol_2ONo．2 2005年 6月 JOURNALOFQINGDAOUNIVERSITY (ET) Jun．2005 ArticleID：1006—9798(2005)02—0001—06 cterizationofPET／E-HDPBlendingSystem GUo Xian—ying (ChemicalEngineeringCollege，QingdaoUniversity，Qingdao266071，China) Abstract：ThemeltrheologicalbehaviorsofthePET／E—HDP(forshortofEasilyHydro- lyzedandEasilyDyedPolyester)blendingsystemsatdifferentblendingratioswerein- vestigated by the capillary rheometer． The E-HDP is derived from polyethylene terephathalate(PET)modifiedthroughcopolycondensationwithsulfonatemoiety，(so— diosulfo)isophthalate(Na—SIP)andiso—phthalicacid(IPA)．Theresultsshowedthatthe apparentviscosityandnon—-NewtonianindexofthePET／E——HDP blendsystem hadthe non—linearitychangewiththechangeoftheblendratioofPET／E—HDP．Theanomalyof theviscousflow activationenergychangewasfoundedasthemassfractionofE-HDP wasabout40 in theblendsystem ，suggestingthepresenceofreversiblecrosslinked structureformedbystrongpolartanglingpointsandthephaseseparationowingtopoor compatibilitybetween thePET andE—HDP Keywords：PET ；E—HDP；rheology；blending；hydrolyzation CLC nalnber：0631．2 Documentcode：A TheEasilyHydrolyzedandEasilyDyedPolyester(forshort l E-HDP)synthesized by the copolycondensation ofpure tereph— thalicacid (PTA)，glycol(EG)，iso-phthalicacid (IPA)and (sodiosulfo)isophthalate(Na—SIP)hasthecharacteristicsofeas— ily dissolving in thewatercontainingalkali[](E-HDP chemical structureseesFig．1． ，Yformolecontentrespectively)．Itcan