NaCl_NH_4Cl_H_2O三元盐水体系相平衡研究.pdfVIP

38 1 2009 1 Jo rnal of Salt and Chem ical Ind stry 11 NaCl NH Cl H O 4 2 崔益顺 (, 643000) : 利用湿渣法研究了NaC l- NH C l- H O三元水盐体系的固液相平衡关系, 测 4 2 定了NaC l和NH C l在水中的溶解度数据 采用 Pitzer法计算了该三元水盐体系相平衡溶 4 解度, 比较了计算值和实验值, 结果基本吻合, 验证了该计算方法 绘制和分析了相图为 热法氯化铵工艺生产提供了理论指导 : 水盐体系; 溶解度; 相图; Pitzer : O658. 6 : A : 1673- 6850( 2009) 01- 0011- 04 St dy on Phase Eq ilibrim of Ternary System NaCl- NH Cl- H O 4 2 CU IY ish n (M aterial and Chem ical Engineering Dept. , Sich an University of Sciences Engineering, Zigong Sich an 643000, Ch ina) A bstrac t: Bym eans of m oist solid m ethod, the phase eq ilibri m of ternary system N aC l- NH C l- H O w as st d ied. The sol b ility data of NaC l and NH C l in water w ere ob tained. Pitzer 4 2 4 m ethodw as tilized to calc late the sol b ility data of phase eq ilibri m of ternary system NaC l- NH C l- H O and m ake a comparison betw een calc lated val e and expermi ental val e, which a-l 4 2 most m atches, and the calc lation methodwas validated. The phase d iagram was protracted and ana- lyzed. It provided academ ic g idance for prod cing amm oni m ch loride by heat m ethod. K ey w ord s: w ater and salt system; sol bility; phase diagram; P itzer , [ 1]