催化氧化法制备硬质氧化蜡.pdfVIP

2 84 Vo l . 2 8 No . 4 200 8 12 J OU R N AL OF L IA ON IN G U N IV E RSIT Y O F PET R OL E U M CH E M ICA L T E CHN O LO GY Dec. 2008 1672 - 6952 ( 200 8) 04 - 0024- 0 3 廖克俭, 张 玲, 丛玉凤, 孙凤娇, 于洪波 ( , 113001) 以石蜡和聚乙烯蜡为主要原料, 进行催化氧化反应, 制得硬质氧化蜡结果表明, 当反应温度为170 , 反应时 为7 h , m( 石蜡) m( 聚乙烯蜡) 为7 3, 催化剂质量分数为0. 01% , 助剂质量分数为1. 0 % , 空气流量 3 为0. 20 m / h 时, 所得氧化蜡的酸值为9. 82 mg( KO H) / g , 皂化值为79 . 19 mg ( K OH ) / g , 针入度为9 . 2 ( 0. 1 mm) , 滴熔点为87 . 4 , 7 5 折光率为 1. 4 53 6, 与天然硬蜡( 巴西棕榈蜡) 的性质非常接近 蜡; 氧化; 硬度; 针入度 T E626 . 88 A P r ep ar at ion of H or niness Ox idized Wax by C at alyt ic Ox idat ion L IA O K e- jian, ZH A N G L ing , CON G Y u- feng, SU N F eng- jiao, YU H ong - bo ( School of Petrochemical Eng ineering , L iaoning Univ ersity of P etroleum Chemical Technology , Fushun L iaoning 11300 1, P. R. China) Receiv e 8 M ay 200 8; rev ise 21 June 2008; accep te 6 S ep tember 2008 Abstract: T he cataly tic ox idatio n ex p er im ent s w er e carr ied out to prep are the ho rniness ox idized w ax fr om p araff in w ax and po ly et hy lene. T he r esult s show th at go od pro du ct s can be obtained under the f ollo w ing co ndition s r eaction temper atur e 170 , r eaction tim e 7 h, m ass ratio of par aff in w ax and polyethylene 7 3, the amount of catalyst 0. 01% , the amo unt of additiv e 1. 0 % , t he air flo w 0 . 20 m3 / h . acid number of t he pro du ct w as 9. 82 mg ( KO H ) / g , saponif icatio n number is 79. 19 mg ( K OH ) / g, penetrat ion is 9. 2 ( 0. 1 mm) , m elting point w as 87 . 4 , index o f refraction ( 7 5 ) w as 1. 4 53 6 . A s comp ared w ith natural h ard w ax ( car nauba w ax ) , their pro per ties