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纸质活性炭纤维的制备及性能表征.pdf
CHINESE J0URNAL oF CHEM ICAL PHYSICS VoLUM E 24.NUMBER 1 FEBRUARY 27,2011
ARTICLE
PreparationandCharacterizati0nofActivatedCarbonFiberfrom Paper
Zong-jianZhang,JiaLi,Fu—shengSun,DickonH.L.Ng,Fung—luenKwong,Shi—quanLiu
a.SchoolofMaterialsScienceandEngineering,UniversityofJinan,Jinan250022,China
b.DepartmentofPhysics,TheChineseUniversityofHoneKong,HoneKon China
(Dated:ReceivedonOctober26,2010;AcceptedonDecember14.2010)
Activatedcarbonfibers(ACFS)withsurfaceareaof1388m /gpreparedfrom paperby
chemicalactivationwithKOH hasbeenutilizedastheadsorbentfortheremovalofmethy—
lenebluefrom aqueoussolution.TheexperimentaldatawereanalyzedbyLangmuirand
Freundlichmodelsofadsorption.TheeffectsofpH valueontheadsorptioncapacityofACFS
werealsoinvestigated.Theratesofadsorptionwerefoundtoconform tothekineticmodel
ofPseudo—second—orderequationwithhighvaluesofthecorrelationcoefficientsfR0.998).
TheLangmuirisotherm wasfoundtofittheexperimentaldatabetterthan theFeundlich
isotherm overthewholeconcentrationrange.Maximum adsorptioncapacityof520mg/g
atequilibrium wasachieved.ItwasfoundthatpH playedamajorroleintheadsorption
process,higherPH valuefavoredtheadsorptionofMB.
Key words:Activatedcarbonfiber,Paper,M icrostructure,Adsorption,Methyleneblue
1.INTR0DUCT10N activatedcarbon fibers.Inthiswork,paperactivated
carbonfiberswerepreparedbychemicalactivationwith
Activatedcarbonsareimportantmaterialsknownfor KOH andcharacterized.regardingtheirtexturalprop-
theirgreatabilitytoadsorbvariousmoleculesontheir ertiesandadsorptioncapacityonmethyleneblue.The
surfacel1—41.Theactivatedcarbonhasbeenproduced equilibrium andkineticdataoftheadsorptionprocess
fromvarietyofbiomassi.e.,woodf5I,ricehuskI6I,cel- ofmethy
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