环烷酸结构组成质谱分析方法.pdfVIP

263 Vol. 26 No . 3 2006 9 JOURNAL OF LIAONING UNIVERSIT Y OF PET ROLEUM CH EMICAL TECH NOLOGY Sep. 2006 : 672- 6952(2006) 03- 000 - 03 2 3 吕振波, 姚立刚 , 张振庚 , 赵杉林 ( . , 300 ; 2. , 300 ; 3. , 3008) : 采用柱色谱和阴离子交换树脂法分离出辽河200~ 430 馏分油中的环烷酸通过电子轰击( EI) 质 谱( MS) 分 得到的环烷酸分别对其中的脂肪酸一环及多环环烷酸进行谱图定性和峰强度数据处理, 得到了有关 结构与组成的分 结果结果表明, 辽河200~ 430 馏分油中环烷酸的相对分子质量分布在 86~ 496, 碳数分布 在C ~ C , 其中双环三环环烷酸的含量较高 34 : 环烷酸; 电子轰击; 质谱; 碳数分布 : TE622. + 4 : A Determination Structure Constitute of Naphthenic Acids by MS 2 3 L Zhen- bo , YAO Li- gang , ZHANG Zhen- geng , ZHAO Shan- lin ( . D ep ar tment of Science and Tech nology , L iaon ing Univ ersity of Petroleum Chem ical Technology , F ush un L iaon ing 300 , P . R . China 2. N o . 3 Ref iner y of P etroChina Comp any L im ited Fushun P etr ochem ical Comp any , F ushun L iaoning 300 , P . R . Ch ina 3. Dep ar tment of Quality I nsp ect ion , N o . R ef inery of P etoChina Comp any L imited F ush un Petr ochem ical Comp any , Fushun L iaon ing 3008, P . R . Ch ina) R eceiv ed 9 June 2006 r ev ised 30 June 2006 accep ted 2 July 2006 Abstract: The naphthenic acids in 200~ 430 distillate of Liaohe crude oil were separated by column chromatogram and anion exchange resin. The analysis results of naphthenic acids w ere obtained by t he use of MS and EI techniques. T he t ype and composition of the naphthenic acids can be classified into fatty acids, mono- , hexa- cyclic naphthenic acids according to their mass spectrum and peak intensit y. The results indicate that the relate molecular w eight distribution of the naphthenic acids in 200~ 430 distill