稀土卤氧化物的近红外及上转换掺杂发光性能与研究.pdfVIP

（9）材料设计、性能表征与服役行为 稀土卤氧化物的近红外及上转换掺杂发光性能研究 夏志国，廖立兵，李静，关鸣 （材料科学与工程学院，中国地质大学（北京），北京，100083） 摘 要：以LnOX （Ln = La, Y, Gd; X = F, Cl, Br ）为代表的稀土卤氧化物是一种兼具卤化物较低声子能量和 氧化物较好稳定性的新型发光材料基质。本文采用传统高温固相方法，研究了NH X 过量比例与产物相结 4 构的关系，在较温和的条件下分别制备出三方或立方相LaOF ，四方相LaOCl 和四方相LaOBr 。光谱研究 表明， Eu3+ 在LaOX (X = F, Cl, Br)基质中均产生特征的红色光致发光。Er3+ 或Yb3+/Er3+ 共掺LaOCl ，可分 别实现黄绿色和红色上转换发光，由此探讨了其可能的上转换发光机理。最近的结果还表明，通过在LaOCl 体系中共掺杂Nd3+ 和Yb3+ 离子，可产生有效的能量传递，产生高亮度的近红外发光，可作为一类很有应用 前景的太阳能电池光谱转换材料。 关键词：无机非金属材料；稀土卤氧化物；上转换发光；近红外发光 Near Infrared luminescence and upconversion luminescence of rare earth oxyhalide XIA Zhiguo, LIAO Libing, LI Jing, Guan Min (School of Materials Science and Technology, China University of Geosciences, Beijing 100083) Abstract：Rare earth oxyhalides representing by the formula of LnOX (Ln = La, Y, Gd; X = F, Cl, Br) can act as suitable host in luminescence materials, which have the low photo energy like halides and good stability. By using the conventional solid-state method, LaOF with trigonal or cubic phase structures, LaOCl and LaOBr with tetragonal structures have been successfully prepared on the basis of the relationship of the addition amount of NH X and the as -obtained phase structures. Photoluminescence investigations indicate that Eu3+ doped LaOX 4 samples will show characteristic red emission near 610 nm. Er3+ single doped or Yb3+/Er3+ codoped LaOCl samples give yellowish green and red upconversion luminescence, respectively, and the possible luminescence is also given. The recent results verify that Yb3+/Nd3+ codoped LaOCl samples give strong near infrared luminescence, and the efficient energy transfer between Yb3+ and Nd3+ is also discu