PEG_SiO_2_TiO_2杂化纤维的制备与表征_马海红.pdf

102 材料导报:研究篇 2010 年11月(下) 第24 卷第11期 PEG/ SiO2T iO2 * 马海红, 周 浩, 贺 力, 于 维, 刘发国, 陶 俊 ( , 230009) 以正硅酸乙酯( TEOS) 和钛酸四 丁酯( TBT) 为无机前驱体, 采 溶胶凝胶法制备了PEG/ SiO TiO 2 2 杂化溶胶,通过提拉法制得杂化纤维,并对其进行了简单表征结果表明, 随钛硅物质的量比的增加或有机相质量的 增加, 溶胶的可纺性变好;有机相与无机相之间通过化学键连接; 纤维直径为40m 左右;T iO 的引入增强了其抗紫 2 外性,杂化纤维的耐热性优于纯PEG PEG SiO T iO 2 2 Preparation and Characterization of PEG/ SiO2TiO2 Hybrid Fibers MA Haihong, ZHOU Hao, HE Li, U Wei, LIU Faguo, TAO Jun ( School of Chemical Engineering, Hefei University of Technology, Hefei 230009) Abstract By solgel method, PEG/ SiO TiO hybrid sols are prepared with tetraethoxylsilane and tetrabutyl 2 2 titanate as inorganic precursor. PEG/ SiO T iO hybrid fibers are prepared by drawing from the hybrid sol and charac 2 2 terized by simple testing methods. The spinnability of the hybrid sol is studied. Structure, micromorphology and property of the fibers are studied by FTIR, optical microscope, UVVis and TG. The results indicate that the spinna bility of the hybrid sols becomes better with increase of the molar ratio of silica and titania or theweight of PEG in the organic phase; PEG is linked with SiO TiO network by chemical bonds; the diameter of the fiber is 40m, its UV 2 2 shielding properties are greatly improved with titania filled in the hybrid fibers, it possesses better heat resistance than pure PEG. Key words solgel metho