低负载量MoS23A分子筛催化剂的制备及其加氢脱硫性能.pdfVIP

第36卷第3期 南京工业大学学报 自然科学版 vol_36N。．3 JOURNALOF TECH NANJING Scjence 11 UNIVERSITY NaturalEdition 2014 11笙!旦 May doi：10．3969／j．issn．1671—7627．2014．03．010 低负载量MoS2／3A分子筛催化剂的 制备及其加氢脱硫性能 刘 彬，潘志刚，陶亚秋，陶露露，李成亮，祝社民 南京工业大学材料科学与工程学院，江苏南京210009 摘要：以四硫代钼酸铵为前驱体，采用等体积浸渍法制备一系列MoS，和Co掺杂的3A分子筛催化剂，并采用x 线衍射仪 XRD 、比表面积分析仪 BET 和扫描电子显微镜 SEM 对催化剂进行表征分析。以噻吩／环己烷为模 拟油，考察催化剂的加氢脱硫 HDS 活性。结果表明：在免预硫化、低负载量 0．5％Mo 的条件下，MoS，／3A分子筛 催化剂的催化活性为97％；Co掺杂的MoS：／3A分子筛催化剂，其HDS活性接近100％；此外，在相同反应条件和制 备方法下，MoS：／3A催化剂的催化活性均高于MoS：／y—A1：O，和MoS：／堇青石催化剂。由此表明，采用3A分子筛 替代传统的Y—A1：O、和蜂窝堇青石作为载体不仅降低了MoS，的负载量，节约了成本，而且还有效地提高了催化剂 的HDS活性；且co的掺杂进一步促进了催化剂活性的提高。 关键词：MoS，；3A分子筛；加氢脱硫；催化剂；Co掺杂 中图分类号：0643．32 文献标志码：A 文章编号：167卜7627 2014 03—0052—05 oflow molecularsieve and SynthesisloadingMoS2／3A catalysts its hydrodesulphurizationperformance LIU Shemin Bin，PAN Yaqiu，TAOLulu，LIChengliang，ZHU Zhigang，TAO ofMaterialsScienceand Tech University，Nanjing210009，China College Engineering，Nanjing seriesof andCo molecularsieve were Abstract：A by MoS2 dopedMoS2／3A catalystsprepared ammonium as obtained were impregnationusing tetrathiomolybdateprecursor．Thecatalystsinvestigated surface electron area BET and microscope SEM ． byX—raydiffraction XRD ，specific scanning The wascarriedoutwith asmodeloilon hydrodesulphurization HDS evaluationthiophene／cyclohexane afixedbedreactor．Resultsindicatedthatthe exhibited catalyticactivity synthesizedcatalysts high thecaseoffree andlow 97％ in prevulcanizationloading 0．5％Mo ．The sieve reachedto 100％．The ofCobalt molecular activity dopedMoS2／3A catalyst up nearly synthesized much thanthe andcordierite higheractivity MoS2／y—A1203 honeycombcatalysts catalystspresented thesimilarmethodunderthesamereactionconditions．It thatthe the with suggestedcatalystby prepared oftheconventionalandcordierite carrierswith3Amolecularsievesof substitution y—A1203 honeycomb lowloaded increasedthe ofCofurther the MoS2 hydrodesulphurizationactivity．Thedoping promoted ofthe catalystactivity． improvement molecular Keywords：MoS2；3A