双施主掺杂对高居里点PTC陶瓷性能的影响.pdfVIP

第10 期 电 子 元 件 与 材 料 Vol.24 No. 10 2005 年10 月 ELECTRONIC COMPONENTS MATERIALS Oct. 2005 研究与试制 R D 双施主掺杂对高居里点PTC 陶瓷性能的影响 郝永德 钟海波 熊 眩 龚树萍 华中科技大学电子科学与技术系 湖北 武汉 430074 摘要:在分别研究了Nb5+ Y3+掺杂对高温PTC 陶瓷性能的影响后 得出结果 Y3+既可作为施主 又可起受主作 用 还可以提高升阻比 Nb5+主要是起施主作用 但可以抑制Pb 的挥发 为了能够使高温PTC 陶瓷整体性能提高 因此结合Nb5+ Y3+各自的优点 用正交法对高温PTC 陶瓷进行了双施主掺杂配方的试验 优选了最佳配方 Nb5+应 该控制在0.06~0.08 之间 Y3+控制在0.08~0.12 之间较好 关键词:电子技术 BaTiO3 系PTC 陶瓷 高居里点 双施主掺杂 铅挥发 中图分类号: TN373 文献标识码:A 文章编号:1001-2028 2005 10-0045-03 Effect of Double Donors Doping on BaTiO -based High Curie 3 Point PTC Ceramics HAO Yong-de, ZHONG Hai-bo, XIONG Xuan, GONG Shu-ping (Dept of Electronic Science and Technology, Huazhong University of Science and Technology, Wuhan 430074, China) Abstract: The effect of Nb5+ Y3+ donor on the properties of high Curie point PTC ceramics was studied and obtained results are found that Y3+ acts not only as a donor, but also as an acceptor, and can also increase the ratio of ñ /ñ ; and Nb5+ max min acts mainly as a donor, but it can decrease the lead volatility. In order to improve the properties of high Curie point PTCR, the Nb5+ and Y3+ donors are doped , and the optimum amount is found that Nb5+ should be controlled in 0.06~0.08, Y3+ in 0.08~0.1. Key words : electronic technology; BaTiO -based PTC ceramics; Curie point; double-donor doping lead volatility