《Application of New Heavy Metals Resistant Porous Binder Material Used in Fluid Catalytic Cracking Reaction》.pdfVIP

China Petroleum Processing and Petrochemical Technology Catalyst Research 2014, Vol. 16, No. 1, pp 35-39 March 30, 2014 Application of New Heavy Metals Resistant Porous Binder Material Used in Fluid Catalytic Cracking Reaction 1,2 1,2 1 2 Zhang Zhongdong ; Liu Zhaoyong ; Yan Zifeng ; Gao Xionghou ; Zhang Haitao2 ; Wang Zhifeng2 (1. State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Qingdao 266580; 2. Lanzhou Petrochemical Research Center, Petrochemical Research Institute, PetroChina, Lanzhou 730060) Abstract: A novel porous binder was obtained from acid-treated kaolin. This new binder possessed abundant meso/macro- pores, good hydrothermal stability and heavy metal resistance. The prepared catalyst using new binder featured low attrition index and large pore volume. The catalysts were contaminated with Ni, V, and tested in a fixed-fluidized bed reactor unit. In comparison with the reference sample, the oil conversion achieved by the above-mentioned catalyst increased by 3.50 per- centage points, and heavy oil yield decreased by 2.86 percentage points, while the total liquid yield and light oil yield increased by 2.82 percentage points and 0.79 percentage points, respectively. The perfect pore structure, good hydrothermal stability and heavy metal resistant performance of new binder were the possible causes leading to its outstanding performance. Key words: fluid catalytic cracking; binder; conversion; porous material; hydrothermal stability; heavy metal resistant 1　Introduction troleum