气相色谱法测定鱼和肉中有机磷农药残留量.pdfVIP

第 40 卷 　第 3 期 理化检验化学分册 Vol . 40 　No . 3 2004 年 3 月 PTCA ( PAR T B : CHEM ICAL ANAL YSIS) Mar . 2004 气相色谱法测定鱼和肉中有机磷农药残留量 赵秋香 , 郑志雯 , 张 　峥 , 冯德雄 胡国昌, 周 　华 , 陈文锐 (暨南大学 化学系 , 广州 5 10632) (广州进口食品卫生监督检验中心) 摘 　要 : 采用气相色谱法测定鱼和肉中有机磷农药残留量 ,对国标法作了部分改进 ,从而使可 测的有机磷农药组份增加一个甲基对硫磷 ,且灵敏度和分辨率均有所提高 , 同时使国标法中未完 全分离的马拉硫磷和对硫磷得到完全分离 。 关键词 : 气相色谱法 ; 改进 ; 有机磷化合物 ; 残留农药 中图分类号 : O657 . 7 　　　文献标识码 : A 　　　文章编号 : 100 14020 (2004) 030 15003 GC D E TERM INA T ION O F R ESIDUAL OR GAN O PHO SPHORU S P EST ICID ES IN M EA T AND F ISH ZHAO Qiuxiang , ZHENG Zhiwen , ZHANG Zhen , FENG Dexiong ( Dep t . of Chem is t ry , J i ′nan University , Guangz hou 5 10632 , China) HU Guochang , ZHOU Hua , CHEN Wenrui ( Guangz hou M unicip al S af ety Cont rol an d Hy g ienic I nsp ection Cent re of I mp orted Food) Abstract : A modification for t he national standard met hod of GCdetermination of residual organop hosp horus p esticides ( GB/ T 5009 . 20 - 1985) is described . Main point s improved are as follows : ① Complete dehydration is achieved by increasing t he mass of anhydrous Na SO to 25g ; ② Temp erature of t he evaporation water bat h is raised to 2 4 60 ℃; ③ Appropriate adj ust ment s are made for t he chromatograp hic conditions including t he GC column , stationary liquid , carrier , temp erature of t he evaporizing chamber and of t he column , t he flowrate of carrying gas and etc . ; ④A programmed raising of temp erature is applied in t he procedure . As comp ared wit h t