离子色谱法同时测定氟_磷酸根和六氟磷酸根离子.pdfVIP

37 7 - V ol. 37 No. 7 2001 7 TCA ( PART B: CHEM CAL A NAL YS S) July 200 1 , ( , 310035) ( ) : 氟磷酸根和六氟磷酸根离子在流速为 0. 25ml min- 1, 淋洗液为0 . 001mol L- 1 Na2 CO3 和0. 005molL- 1 NaOH 溶液, 在离子色谱仪上能较好地分离氟磷酸根和六氟磷酸根离 子的检出限分别为7. 29, 70 . 5 和295ng m l- 1, 该 法具有良好的线性, 测定结果有较好的重现性 样品测定结果满意 : 离子色谱; 氟离子; 磷酸根离子; 六氟磷酸根离子 : O657 . 7+ 5 : A : 1001-4020( 2001) 07- 0313- 03 S M ULT ANEOU S ON CH ROM AT OGRAPH C DET ERM NAT ON OF FLU OR DE PH OSPHAT E AND HEXAFLU OROPHOSPHAT E ONS DU Han-gen (H angzhou Institute of Commerce, Hangzhou 310035, China) RUAN Xiu-xiu, HU Zhen-liang (Dep artment of Chemistry, Zhej iang University, Hangz hou) Abstract: t is reported that fluoride, phosphate and hex afluorophosphate ions were successfully separated by ion- chromato graphy using a mix ed eluent composed of 0. 001molL - 1 N a CO and 0. 005molL- 1 NaOH at a flow rate of 0 . 2 3 25mlmin- 1. T he detection limits ( S/ N = 3) found ar e 7 . 29, 70 . 5 and 295ngml- 1 for fluoride, phosphate and hex- afluoro phosphate ions respectively. Good linear ity and r epeatability are prov ed by exper imental results. T he above men- tioned method has been satisfactorily applied to the analysis of lithium hexafluorophate. Keywords: on- chromatog raphy; F luor ide ion; Phosphate ion; Hex afluorophosphate ion , , [ 1~ 3] , [ 4] , LiPF LiAsF 6