X射线荧光光谱法同时测定地质样品中铌钽锆铪铈镓钪铀等稀有元素.pdf

2010 2 Vo.l 29, No. 1 February 2010 ROCK AND M INERAL ANALYSIS 74 76 : 0254-5357( 2010) 01-0074-03 X射线荧光光谱法同时测定地质样品中铌钽锆铪铈镓钪铀等稀有元素 * 刘江斌, 赵 峰, 余 宇, 党 亮, 张旺强 , 陈月源 (, 730050) : 采用粉末压片法制样, 选用标准样品, 以经验 数和散射线内标法校正基体效应和元素谱线重叠干扰, 使用 ZSX Prmi us X 射线荧光光谱仪对一般地质样品中的铌钽锆铪铈镓钪铀等稀有元素进行测定,分析结果与标准值和参 考值吻合, 12次测定的相对标准偏差(RSD)小于 10% : X 射线荧光光谱法; 稀有元素; 粉末压片; 地质样品 : O657. 34 : B SimultaneousDetermination of Nb, Ta, Zr, Hf, Ce, Ga, Sc andU in Geological Samples byX-ray Fluorescence Spectrometry * LI UJiang-bin, ZHAO Feng, YU Yu, DANG L iang, ZHANG Wang-qiang , CHEN Yue-yuan ( Lanzhou Testing and Q ua lity Superv ision Cente r for Geo log ica l and M ine ra l P roducts, T he M in istry o f Land and Resou rce s, Lanzhou 730050, Ch ina bstract: A X-ray fluorescence spectrom etricm ethod for the determ ination of Nb, Ta, Zr, H f, Ce, Ga, Sc and U in geological sam plesw ith pressed pellet sam ple preparation technique has been developed. ZSX Prmi us instrum ent was used. The matrix effectw as corrected by classic coefficient m ethod and internal standard m ethod using scattered lineswas used. The resu ltsw ere in agreem entw ith certified values and reference valuesw ith precision of less than 10% RSD( n= 12). K ey words: X-ray fluorescence spectrom etry; rare elem ents; pow der pellet; geological samp le , , , , , , , 1 实验部 [ 1- 2] ; , 1. 1 仪器及测量条件 ZSX Prmi us X ( ), , 4. 0 kW X ; () , ( Ta 1 500 g /g, U 100 g/ g), 1. 2 样品制备 ,