木素化学解聚产物特征及机理研究进展.pdfVIP

研究开发 R D 木素化学解聚产物特征及机理 研究进展 ⊙ 王兴 周景辉 （大连工业大学轻工与化学工程学院，辽宁大连 116034） 王兴，硕士研究生；主要研究方 向：制浆造纸清洁生产与植物资 The research progress on characteristics of lignin’s 源高值化利用。 chemical depolymerization products and its depolymerization mechanism ⊙ WANG Xing, ZHOU Jing-hui (Institute of Light Industry and Chemical Engineering, Dalian Polytechnic University, Dalian 116034, Liaoning, China) 摘 要： 综述了近几年来木素化学解聚产物特征及机理的研究进展，简要介绍木素大分子形成 过程、结构单元、连接方式及三相产物 （液相、气相、固相）在热液解聚、加氢解聚、催化氧化解 聚等解聚工艺下的得率、组成成分等特征，重点介绍了液相产物在不同木素来源、不同解聚工艺 下的得率及组成成分等特征，并介绍了化学解聚产物的解聚机理。最后，总结了当前木素化学解 聚过程中存在的问题，提出了未来木素解聚研究方向，展望了木素利用的发展前景。 关键词： 木素；解聚；热解；生物质 Abstract: The research progress in recent years on the characteristics of lignin’s chemical depolymerization products and the depolymerization mechanism were reviewed in this paper. Brief introduction was made of the lignin macromolecule formation process, structure unit, connecting way and the yield, composition, and of the characteristics in three-phase product (liquid phase, gas phase and solid phase) by hydrothermal depolymerization and hydrogenation depolymerization and catalytic oxygen depolymerization processes. The characteristics of liquid- phase product by the process of different sources of lignin and different depolymerization methods were mainly discussed; t