MnO_2乙炔黑的超声化学制备与性能.pdf

第39卷第5期 电 池 V01．39，No．5 2009年lO月 BATTERYBIMONTHLY 0ct．，2009 n M02／乙炔黑的超声化学制备与性能 文建国1，阮湘元1，周震涛2 摘要：分别采用超声化学法和化学混合法制备了Mn02／乙炔黑复合电极材料。XRD结果显示：超声化学法制备的粉体呈 均匀分散，并能改善电极材料的电化学动力学可逆性，-3乙炔黑含量为15％时，可使复合电极的电化学比电容提高两倍。 关键词：超声化学； Mn02；乙炔黑； 电化学电容器；复合材料 中图分类号：TM533文献标识码：A 文章编号：1001一1579(2009)05—0275—03 and of black performance Sonochemistrypreparation Mn02／acetylene WEN Zhen—ta02 Jian．Gu01，RUAN Xiang-yuanl，ZHOU andEnvironmental (1．cDf姆ofChemistry Engineering，DongguanUniversityofTechnology， MaterialsScienceand 523808，China；2．纠姆of Engineering， Dongguan，Guangdong SouthChina 510640，China) UniversityofTechnology，Guangzhou，Guangdong via methodandchemi- Abstract：Theelectrodematerialsof black(AB)were composite Mn02／acetylene preparedsonechemistry eal showedthatthe method astructureof mixingmethod，respectively．XRDanalysis powderpreparedbysonochemistrypresented chemicalmethod of resultsofSEMandelectrochemical a-Mn02．the Mn02．The powderpreparedby mixing WaB锄amorphom radiationcouldmake withconductive indicatedthattheultrasonic Mn02 experiment homogeneomdispersion agent，couldimprove of electrodematerial．Theelectrochemical ofthe electrode electroche