Li+在Li43Ti53O4电极中嵌入过程的动力学研究.pdf

电池工业 Li+在Li柑i驺04电极中嵌入过程的动力学研究 刘素琴‘，管海英，黄可龙 (中南大学化学化工学院。湖南长沙410083) 摘要：采用直接融盐法合成了尖晶石化合物蚶i∞。，采用x一射线衍射分析咖)和扫描电镜 (sEM)对其进行物相分析。采用交流阻抗测试(EIS)研究了新鲜电极首次嵌锂过程中的电化学阻抗特 征。通过选取适当的等效电路拟合实验所得的电化学阻抗谱数据，获得了首次嵌锂过程中固体电解 质相界面膜(SEI)电阻、电荷传递电阻、Warburg扩散系数、累积电容和锂离子扩散系数随电极极化电 位的变化规律。 关键词：锂离子动力学；锂离子电池；尖晶石化合物Li4／3Tis／304；交流阻抗 intercalationinto ElectrochemicalkineticsofLi-ion electrode L讲’is／304 spinel LIU Hai-ying，HUANGKe-long Su-qin*,GUAN South 410083,ChinaJ ChemistryChemicalEngineering,CentralUniverssty,Changsha，Hunan (CoUegeof directmolten-salt certified Abstract：Theof by method，W88by compoundspinelLi棚∞04synthesized and electron firstintercalationofthe diffraction I如ITi∞04 X—ray scanning microscopy．The spinel electrodewasstudied electrochemical using impedance equivalent circuitswere tofitthe data．Basedonthe ofthe results，thedependence proposed experimental fitting resistanceof interealation resistanceofSEIfilm，the transfer,thecoefficient，出e charge Warburg andthechemicaldiffusioncoefficienton wereobtained． capacitance potential words：H-ion kinetic；H-ion Key battery；spinel娜5n04；electrochemical