MoSi_2对注凝成型HfB2超高温陶瓷材料性能的影响.pdf

28卷第5期 硅 酸 盐 通 报 v01．28N。．5 高温陶同皿l删瓷材料 MoSi2对注凝成型HfB2超 性能的影响 唐竹兴，杨晴晴，杨赞中 (山东理工大学材料科学与工程学院，淄博255049) (5％一15wt％)MoSi2超高温陶瓷坯体，密度达到4．25s／cm3以上，在氩气气氛下1950oC保温30min烧成。采用X 射线衍射仪、扫描电镜等分析方法研究了添加剂MoSi：对HtB：超高温陶瓷材料性能的影响、烧结体的物相组成和 显微结构。结果表明：添加剂MoSi：可有效促进HfB：超高温陶瓷材料的致密化，随着MoSi：加入量的提高，HfB：超 高温陶瓷材料的力学性能不断提高，当加入量为15％时，可得到显微硬度为9．8GPa，抗弯强度为389．7MPa，断裂 韧性为3．7MPa·in“2的HfB2超高温陶瓷材料。 j关键词：注凝成型；超高温陶瓷材料；显微结构；力学性能 中图分类号：TQl74 文献标识码：A Effectsof Additiveonthe of Ultra MoSi2 PropertiesHfB2 High CeramicsProduced Temperature byGel—gasting TANG Zhu—xing，YANG俄ng—qing，YANGZan-zhong and ofMaterialsScience of (Department Engineering，ShandongUniversityTechnology，Zibo255049，China) bodiesofthe ultra Abstract：，I．}legreen HfB2-(5％-15wt％)MoSi2hightemperatureceramics(UHTCs) were when was contentof system producedbygel·castingpH 10．9，the 8vol％andthesolidcontentofthe was40vol％．the ofthe bodieshadachieved slurry density green above4．25 weresinteredina multi—furnaceundera at1950 s／cm3．They high flowingargonatmosphere ℃for30min．Theeffectsof onthe were MoSi，additions ofHfB，UHTCsstudied．The properties phase withan of were diffractometerandthemicrostructuresthesinteredUHTCS compositionsanalyzed X．ray were