298_15和308_15K温度条件下甘氨_省略_在电解质溶液中的热力学性质的研.pdfVIP

2006 64 Vol. 64, 2006 6 , 579583 ACTA CHIMICA SINICA No. 6, 579583 · · 298.15 308.15 K : * ( 310027) 298.15 308.15 K KCl-NaCl-, V V , Φ Φ ∆ V N . trs Φ h . , ; . . ; ; Study on Thermodynamic Properties of Glycylglycine in Aqueous Electrolyte Solutions at 298.15 and 308.15 K: Volume Properties LIN, Gui-Mei BIAN, Ping-Feng LIN, Rui-Sen* (Department of Chemistry, Zhejiang University, Hangzhou 310027) Abstract Apparent molar volumes V of glycylglycine in aqueous KCl and NaCl solutions have been Φ obtained from densities at 298.15 and 308.15 K measured with a vibrating-tube densimeter. These data have been used to deduce partial molar volumes of transfer ∆trs V from water to different salt water mixtures. Φ ∆trs V values are positive. This result arises from the interaction of KCl and NaCl with the charged centers Φ of glycylglycine. The positive ∆trs V of glycylglycine shows that salts in the concentration range studied Φ will stabilize the globular protein. The results show that ∆trs V depends less on temperature. The interaction Φ between the charged centers of glycylglycine and ions dominates other forms interactions. The results have been explained using the cos