杂质离子对Alite晶格畸变和结晶形态的影响.docVIP

杂质缺陷诱导阿利特晶胞常数改变与多晶转变的研究 管宗甫1 ，陈益民2， 郭随华2 ，秦守婉2，朱晓燕2 （1. 郑州大学材料科学与工程学院，郑州，450052；2.中国建筑材料科学研究院，北京，100052） 摘要：阿利特（硅酸三钙C3S固溶体）是水泥熟料中最重要的矿物，某些杂质离子可以稳定其多晶形中的三方R型，具有较高的水化活性。杂质离子固溶进入C3S晶格，形成杂质缺陷，这些缺陷引起C3S晶格常数的变化。实验研究显示C3S的晶格常数变化与其对称性有着对应关系，从而提出了一种由杂质缺陷引起晶格常数相对变化的计算方法，用于预测C3S固溶体和阿利特可能的稳定晶型。在实验室合成了不同掺杂的C3S固溶体单矿物，并从实验熟料中萃取了阿利特。对样品进行了晶格常数相对变化计算和晶型预测，并用XRD分析了它们的晶型。计算预测结果和XRD分析结果之间有较好的对应关系。XRD分析表明，纯C3S的对称性最差，属于三斜晶系；当C3S中P2O5固溶量在0.4%时C3S固溶体为单斜M1型；当CaF2掺量在1.0%时C3S固溶体为M1型，当CaF2掺量提高到2.0%时C3S固溶体是R型；复合掺加氟磷对改变C3S固溶体对称性有显著作用，只要掺杂0.4%的 P2O5 和 0.7w% 的CaF2既可使R型C3S固溶体在室温下稳定。对熟料中萃取阿利特的分析表明，普通熟料中萃取的阿利特稳定晶型属于M1型；含氟磷的熟料中阿利特是以R型为主的R型和M3型的混合体。分析结果验证了计算预测结果。 关键词：掺杂； 缺陷；晶格常数改变；阿利特；多晶型 中图分类号：TQ172.11 文献标示码： A 文章编号：0454—5648(2006)02— THE CRYSTAL LATTICE CONSTANT CHANGE AND POLYMORPH OF ALITE CAUSED BY IMPURITY DEFECTS GUAN Zongfu1,2, CHEN Yimin2,GUO Suihua2,QIN Shouwan2, ZHU Xiaoyan2 (1.Material Science and Engineering Institute, Zhengzhou University, Zhengzhou 450052; 2. China Building Materials Academy, Beijing 100024, China.) Abstract: Alite is a most important mineral in portland clinker. The rhomboheral pattern of alite stabled by certain impurity ions is more hydratable. The impurity ions form defects in alite crystal lattice. The defects can induce the crystal lattice constant change. The crystal lattice constant change caused by some impurity defects may advance the symmetry of alite. Calculation and test indicated that the symmetry of alite was related with the crystal lattice constant change. So, a calculating method about the crystal lattice constant change brought by doping ions was suggested. With the calculated results, the possible polymorphs of alite or C3S solid solution can be guestimated. Pure C3S was synthesized and C3S solid solutions that contain certain ions were prepared. Alites were extracted from experimental clinkers. The polymorphs of the samples were examined by XRD at special 2θangles and deduced with the calculations about the crystal lattice constant changes. The