青藏高原湖泊沉积正构烷烃单体氢同位素比值地气候意义.docVIP

青藏高原湖泊沉积正构烷烃单体氢同位素比值的气候意义 摘要：本文分别在青藏高原南部的大枪勇错、空姆错，中部的纳木错以及东北部的克鲁克湖和小柴达木湖钻取了浅岩芯，通过将表层沉积物中陆源正构烷烃单体 (n-C25-31) 的(D 值与当地生长季节大气降水的(D 值进行比较，发现陆源正构烷烃记录了生长季节降水的同位素信号。陆源正构烷烃与大气降水间氢同位素表观分馏在-45‰ 至-95‰之间，通过对比欧洲-130‰表观分馏值，可以看出青藏高原地区陆源正构烷烃与大气降水间表观氢同位素分馏小很多。 ??? 通过将表层沉积物中水生生物来源的正构烷烃单体 (n-C17-23) 的(D 值与当地湖水的(D 值进行比较，发现沉积物中水生生物来源的正构烷烃单体没有记录源水的同位素信号。水生生物来源的正构烷烃与湖水间的氢同位素分馏在-30‰ 至-170‰之间，沿断面分馏差异大，通过对比欧洲稳定的-157‰分馏值，可以看出不同地区源水与水生生物来源的正构烷烃间的氢同位素分馏可能不一定稳定在-157‰。 ??? 通过将空姆错的时间跨度约50年、7年间隔的岩芯剖面中陆源正构烷烃单体(n-C25-31) 的(D 值与当地气象站气候要素进行比较，发现陆源正构烷烃单体(D 值记录了生长季节的气温信号。 Abstract：??Shallow sediment cores were sampled from Qiangyong Glacier Lake,Kongmu Co Lake,Nam Co Lake, Keluke Lake and Xiao Qaidam Lake along a S-N transect on the Tibetan Plateau. (D values of terrigenous n-alkanes (n-C25-31) extracted from surface sediments are compared to that of precipitation, showing that terrigenous n-alkanes record the precipitation signal during the growth. The fractionation between precipitation and terrigenous alkanes cover a range from -45‰ to -95‰. By comparison with the fractionation of -130‰ in the Europe, it shows that the hydrogen isotopic fractionation between meteoric water and terrestrial n-alkanes on the Tibetan Plateau is much smaller. ((( (D values of aquatic derived n-alkanes (n-C17-23) extracted from surface sediments are compared to that of lake water, showing that these biomarkers do not record lake water signal. The fractionation between lake water and aquatic alkanes cover a range from -30‰ to -170‰. By comparison with the constant fractionation of -157‰ in the Europe, it shows that the hydrogen isotope fractionation between source water and aquatic n-alkanes may not be necessarily constant at -157‰ in different regions. ((( (D values of terrigenous n-alkanes (n-C25-31) extracted from a profile spanning the past near-50 years at 7-year resolution from Kongmu Co Lake are compared to the climate elements of local weather stations, showing that these biomarkers record the air temperature signal