超微5A分子筛的合成及其对铬离子的吸附.docVIP

论文题目：超微5A分子筛对重金属离子的吸附研究 专 业：化学工程与工艺 本 科 生：张 赛 （签名） 指导老师：杨建利 （签名） 摘 要 工业废水处理是目前废水处理的难点之一。废水中含有大量的重金属离子，对人体的危害巨大。超微分子筛是目前分子筛领域的主要发展趋势之一。由于晶粒尺寸极小，外表面积和表面原子数增大、表面能增高、表面酸量增大、外露孔口增多、孔道缩短、孔容及孔隙率增大，其对金属离子的吸附能力也将增强。探讨超微分子筛吸附能力和最优化吸附条件，将是目前分子筛应用于工业废水处理领域的一个重要研究课题。 本研究采用蔗糖法和微波法两种不同方法制备超微5A分子筛，超微5A分子筛具有更强的吸附性能。并且确定超微5A分子筛的最优化吸附条件为：常温25℃、pH=11、最佳吸附时间大于1h。对铬离子的吸附试验表明，超微5A分子筛对铬离子的最大吸附量为0.037mg/mg；拟合结果显示，超微5A分子筛对离子的吸附满足Langmuir 吸附等温式，其吸附速率满足二级吸附速率方程。 关键词：超微5A分子筛重金属离子铬离子吸附 研究类型：应用基础 Subject : The Study of Adsorption of Heavy metal ions on Ultramicro 5A molecular sievSpecialty : Chemical Engineering and Technology Name : Zhang Sai (Signature) Instructor: Yang Jianli (Signature) ABSTRACT Industrial wastewater treatment is one of the difficulties of wastewater treatment. Wastewater contains a lot of heavy metal ions，which is harmful for human. Ultra-molecular sieving is a main trend in the development of molecular sieving field at present. Because the crystalline grain size is very tiny, its outer surface area and the atom number of surface increased sharply, surface energy accreted, surface acid amount augmented, exposed ostiole augmented, aperture shortened, pore volume and pore rate improved, the adsorption capacity for metal ions will also change. It is an important research topic in the field of wastewater treatment industry to investigate the adsorption strength and the optimal conditions of ultramicro molecular sieving. This study adopts sugar and microwave method to prepare ultramicro 5A molecular sieving. Using XRD, IR spectra and SEM analysis, the results show that both methods can be prepared by ultramicro 5A molecular sieving. Through adsorption experiments show that ultramicro 5A molecular sieving has a stronger adsorption. The optimum adsorption conditions were: temperature 25 ℃ and pH = 11, more than 1h. Adsorption test for Cr showed that the maxim