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第6期 陈亚洪 ，等 ·软段结构对脂肪族聚氨酯弹性体的结构与性能影响 ·21· mentedthermoplasticpolyurethaneelastomerswithtwodifferentsoft 3279—3287 segments[J]．JApplPolymerSci，1999，73：345—352 8 LuoN，WangD N ，YingSK．Hydrogenbonding betweenurethane 5 张立伟，王贵友，胡春圃，等．催化剂对 IPDI制备的脂肪族聚氨 andurea：Band assi—gnmentforthecarbonylregionofFT—IR spec— 酯弹性体结构和性能影响[J]，高分子材料科学与工程，201l， trum[J]．Polymer，1996，37(14)：3045—3047 27f7)：50—53 9 ZhangJ，HuCP．Synthesis，characterizationandmechanicalprop- 6 SomaniKP，PatelN K，KansaraSS，eta1．Theeffectofchainlength ertiesofpolyester-b·ased aliphaticpolyurethaneelastomerscontai- ofpolyethyleneglycolonpropertiesofcastoroilbasedpolyurethane ninghyperbranchedpolyestersegments[JJ．EurPolymJ，2008，44： elastomers[J]．JMacromSci：A，2006，43：797—811 3708—3714 7 FerrerM CC，BabbD，RyanA J．Characterisationofpolyurethane networksbasedonvegetablederivedpolyol[J]．Polymer，2008，49： 收稿 日期 2014—08—24 修回日期 2014一l0—24 EffectofSoftSegmentontheStructureandPropertiesofAliphaticPolyurethaneElastomer ChenYahong ShenQuanjing WangGuiyou (1．PanAsiaTechnicalAutomotiveCenterCo．Ltd，Shanghai201201，China)(2．Schoolof MaterialsScienceandEngineering，EastChinaUniversityofScienceandTechnology，Shanghai200237，China) Abstract：Thealiphaticpolyurethaneelastomers(PUE)basedisophoronediisocyanate(IPDI)wereprepared fromfourkindsofsoftsegmentpolypropyleneglycol，poly(tetramethyleneetherglycol(PTMG)，poly(neopentyl glycoladipate)glycolandpoly(diethyleneglycol—co—trimethylolpropaneadipate)glycol，respectively．Thestruc— tureandpropertiesofthesePUEswereinvestigatedbyFT—IR，DSCandTGA，etc．TheresultsshowedthatPUEpre— paredrfom PTMG hadthehighestcrosslinkdensityandthelowestdegreeofhydrogenbondinurethanecarbony1． However，PUEsbasedonpolyesterglycolhadbetterthermalpropertiesandagingpropertiesthantheP