快速热压法制备ZnO纳米颗粒掺杂Bi2Te2.7Se0.3材料及热电性能的研究.pdfVIP

快速热压法制备ZnO纳米颗粒掺杂Bi2Tez7Se0.3 材料及其热电性能研究 蒋 阳 1黄 鉴 1 仲洪海1 戴礼兴2 1.合肥工业大学材料科学与工程学院，合肥2300092安徽马鞍山华东超硬材料研究所，马鞍山243012 摘 要：采用粉末冶金快速热压法将ZnO纳米颗粒掺杂进入Bi2Te27Se0.3基体，得到n-(ZnO)x(Bi2Te27Se0.3)1-x（x为 ZnO摩尔分数，x=0、0.1、0.15、0.2）块体合金材料。在300-550K范围内研究了ZnO掺杂量和热压工艺对该材料热电性 能的影响。结果表明在压制压力为20MPa、775K下烧结20min获得了相对密度达到95％，晶粒尺寸在1μm左右的块体 材料。当ZnO掺杂量x(=)0.2，电导率在300K时达到1067S/cm。Seebeck系数在473K时达到202μV/K，功率因子在 300K时达到32.7μW/(cm·K2)，该性能已具备了实用价值，为进一步的热电器件研制打下基础。 关键词：Bi2Te3基热电材料;ZnO; 快速热压法;Seebeck系数 ;电导率;功率因子 ’IHJM{，n__LCJ^1 影响。由图3(a)可以； ！由于在750K之前是 当烧结温度超过75( }力作用下加快了颗I [1]IhteshamC.On-chipco~ moelectrics[J].NatureNa Properties Research ofZnO Nanoparticles Doped Bi2Te2.7Se0.3ThermoelectricMaterialsviaRapidHot-press ingMethod JIANGYang1HUANGJian1ZHONGHonghaiDAILixing2 1.SchoolofMarerialScienceandEnginnering,HeFeiUniversity of Technology, Hefei 230009;2.Maanshan Huadong Super Hard MaterialsResearchInstitute,Maanshan243012 Abstract:N-(ZnO)x(Bi2Te27Se0.3)1-x(x=0,0.1,0.15,0.2) alloyswereperparedbydopingZnOnanopowdersintoBi2Te2.7Se0.3 alloysbypowdermetallurgyrapidhot-press.Theinfluenceofdifferent ZnO content and rapid hot-pressing sintering on thermoelectric propertiesatdifferenttemperature (300～550K)wereinvestigated.Re sultsshowedthattherelateddensitiesofthesamplesachievedover 95％ ofthetheoreticdensities,andtheaveragegrainsizeofabout 1μ mat775Kfor20minutesunder20MPa.TheSeebeckcoefficient reachedthemaximumvalueof202μ V/Kat473Kandtheelectrical conduetivityandpowerfactorreachedthemaximumvalueof1067S/cm and32.7μW/ (cm ·K2)at300K,withxvalueof0.2,ourwork showedenoughpragmaticvalue,whichlaidthefoundationforfurther studyofthermoelectricdevice. Key words:Bi2Te3 matrix thermoelectric materials; ZnO;rapid hot-press;Seebeckcoefficient;electricalconductivity;powerfactor