双季铵盐类缓蚀剂的研究进展_宋伟伟.pdf

化 工 进 展 ·842 · CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 2011 年第 30 卷第 4 期 进展与述评 双季铵盐类缓蚀剂的研究进展 宋伟伟，张 静，杜 敏 （中国海洋大学化学化工学院，海洋化学理论与工程技术教育部重点实验室，山东青岛 266100 ） 摘 要：简述了双季铵盐类缓蚀剂在金属腐蚀领域的研究进展。指出双季铵盐是一类新型的阳离子Gemini 表面 活性剂，由于具有低毒、较好的表面活性和良好的水溶性等特点，作为缓蚀剂具有广阔的应用前景。根据分子 结构的不同，可以把双季铵盐分为对称型烷基双季铵盐、对称型杂环双季铵盐和不对称型双季铵盐，详细介绍 了三类双季铵盐的缓蚀性能测试结果。指出双季铵盐类缓蚀剂的研究还缺乏系统性，合成环保易降解的双季铵 盐、缓蚀机理研究和工业应用将成为今后双季铵盐类缓蚀剂的研究重点。 关键词：双季铵盐；缓蚀剂；腐蚀 中图分类号：TG 174.42 文献标志码：A 文章编号：1000 –6613 （2011 ）04 –0842 –06 Research progress of bisquaternary ammonium compound inhibitors SONG Weiwei ，ZHANG Jing ，DU Min （Key Laboratory of Marine Chemistry Theory and Technology，Ministry of Education ，College of Chemistry and Chemical Engineering，Ocean University of China，Qingdao 266100，Shandong，China ） Abstract：The research progress of bis-quaternary ammonium salt as corrosion inhibitor is reviewed. Bis-quaternary ammonium salt is a new kind of cationic Gemini surfactant. Due to its low toxicity ， good surface activity and good water solubility ，it is a promising corrosion inhibitor. According to molecular structure ，bis-quaternary ammonium salt is classified into three categories ：symmetrical alkyl bis-quaternary ammonium salt ，symmetrical heterocyclic bis-quaternary ammonium salt ，and non-symmetrical bis-quarternary ammonium salt. The testing results of corrosion inhibition of such three categories are summarized. The research of bis-quaternary ammonium salt is not systematic ，and future research will focus on environment-friendly bis-quaternary ammonium salt ，inhibition mechanism and industrial applications. Key words：bis-quaternary ammonium salt ；cor