大环双核Cu催化剂的制备和催化性能.pdfVIP

27 1 精 细 化 工 V o .l 27, N o. 1 2 0 1 0 1 FINE CHEM ICALS Jan. 2 0 1 0 * Cu( ) 周灿洪, 蒋登高, 王学猛, 谢艳新, 付丽丽 ( , 4 50001) : ( ) { [ Cu ( ) aneN5 ] 2 ( DDS) } ( C lO4 ) 4, , , : O2 5 mL m in, 4 mL , 2 m g, 12 h, 338 K, 12 mL 659% , 783% : ( ) ; ; ; 21; ; : TQ 2035; TQ 22423 : A : 1003- 5214 ( 2010) 0 1- 00 84 - 05 Synthesis of Bis(macrocyclic)Cu ( ) Complexes and Its Catalytic roperties ZHOU C anhong, J IANG Denggao, WANG X uem eng, X IE Y anx in, FU L ili (Schoo l of Chem ical and E nergy E ng ineer ing, Zhengzhou Un iv ersity, Zhengzhou 45000 1, H enan, Ch ina ) Abstract: B is( m acrocyc lic) d icopper( ) comp lexes w as syn thesized and used as a catalyst. It w as characterized by e lem entary ana lysis and infrared spectrum techn ique. Under the atm ospheric pressure of mo lecular oxygen, the process of cyclohexene ox idat ion reaction by O2 u sing { [ Cu ( ) aneN5 ] 2 ( DDS ) } ( C lO ) as a catalyst to synthesize 2cyclohexene1one w as investigated. E ffects o f m any 4 4 factors on the ox idation reaction w ere discu ssed. The op tmi um reaction cond itions w ere obta ined: the am ount o f catalyst w as 2 m g, react ion t mi e w as about 12 h, reaction tem perature w as about 338 K, and the vo lum e of so lven tw as about 12 mL, according to the condit ions: vo lum e of O w as about 5 mL m in, 2 vo lum e of substrate was 4 m L. On the