对聚合物玻璃化转变的几点新认识_何平笙.pdf

154 2006 2 http: 何平笙 朱平平 杨海洋 ( 230026) , , rrhenius , WLF WLF Some New Understandings on Glass Transition of Polymers He Pingsheng, Zhu Pingping, Yang Haiyang ( Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei 230026) Abstract The glass transition of macroscopic single crystal and single_chain crystal of polymer is discussed based on definition of glass transition. The temperature dependence of glass transition does not obey the general rrhenius equation, on the other hand, WLF equation can be considered as a special temperature dependence of glass transition of polymer with segment motion. The glass transition of two_dimensional polymer film is introduced as well. Key words Polymer, Glass transition, WLF equation, Single crystal of polymer, Single_chain crystal,Rubbery state in two_dimensional polymer film ,, [1~ 3] , ,, Tg , :() , () , , [4] 80 , , 1 Arrhenius , WL ,, , , , ,, , , ,, , , 64, , E_mail: hpsm@ ustc. edu. cn 2005-06-09, 2005-08-01 http:www. 2006 2 155 WLF : lgaT = - 174( T - Tg )(516+ T - Tg ) ,, rrhenius ,WLF , ,,, , , [5] WLF , 2 100% ,() , ( ) ,,, , , , 50Keller ( 001%) , , , , , ,, , ,, , , , , , , , , [6] ,, , , , , , ( )_2, 4__1,6_ (polybis( 2,4-hexadiyne_1,6_diolp _tosylate, PTS) ()_2,4__1,6_ (TS) ,10 102mm, 26mmTS