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ChinaPetroleum andPetrochemical
Processing Technology
ScientificResearch 8-14 December
201I,V01.13,No.4,PP 30,2011
Effectsof OlefinsFormation
Light duringCatalytic
of
Pyrolysis
n—-Heptane
Cheng Xiaoli
Xiaojie;XieChaogang;Wei
ResearchInstitute
(SINOPEC ofPetroleumProcessing,Beijing100083)
Abstract:Theinfluenceofzeolites仇lctureand reaction and ratio)
processparameters(includingtemperaturecatalyst/oil
onrolesforformationof and inthecourseof wasstudiedinasmall-
ethylenepropylene catalyticpyrolysisof胛-heptane
scalefixedfluid unit.Testresultshaverevealedthat totheUSYzeoliteandBeta
catalyticcracking compared zeolite,the
catalytic of inthe oftheZRPzeolite canresultin and of
pyrolysisn-heptanepresence catalyst higheryieldselectivityethyl-
eneand reaction anda ratiocan theformationof
a
propylene,whilehigher temperaturehighercatalyst/oil promote ethylene
and to in
of formationreactionismoresensitivethe
propyleneduringcatalyticpyrolysisn-heptane.Theethylene changes
reaction the in moreinfluentialtothe formationreaction.This
r
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