Synthesis of hollow coreshell nanostructures by nucleaitongrowth control.pptVIP

Synthesis of hollow/core-shell nanostructures via nucleation-growth control 报告人：方亮 2004级 导 师：张涛 研究员 Outline Introduction of hollow/core-shell nanostructures Synthesis of hollow/core-shell nanostructures via nucleation-growth control Application of core-shell nanostructures Future directions Conclusion Introduction of hollow/core-shell nanostructures Intrinsic structure characteristic Application drug delivery systems nanoreactors harvesting solar energy in the visible range … Normal synthesis approach The template-directed/mediated synthesis pre-occupation removal of the template by calcinations or dissolution with solvents The emulsion synthesis crystallization on water-organic phase interfaces leaching water by a large amount of organic reagent Template-free synthesis Nucleation-growth control Kirkendall type diffusion Crystallization-induced shrinkage Template-free synthesis Nucleation-growth control Kirkendall type diffusion Crystallization-induced shrinkage Nucleation and growth Growth by recrystallizationOstwald ripening and Oriented attachment TiO2 (Ostwald ripening) Requirement polycrystal aggregation TiF4 1.33-2.67mM nucleation control monodispersed nanocrystallites growth control observable recrystallization hydrolysis rate TiF4TiCl4 Ostwald ripening/growth by diffusion long time Characteristic Channel delivery systems a refill process Other samples (Ostwald ripening) Application of core-shell nanostructuresnanoreactors Au@TiO2 nanoreactor (Ostwald ripening) Au@TiO2 nanoreactor Future directions preorganization design of primitive nanocrystallites effective control of pore structure and channel size chemical modification of channel walls for the reactor shells higher catalytic activity could be attained with smaller metal nanoparticles Conclusion Symmetric and asymmetric hollow/core-shell nanostructures were synthesized via template-free nucleation-growth control process. Resultant core-shell nanostructures coul