298.15 K下Li-Ti-H2O系φ-pH图及Li4Ti5O12的合成.pdf

第20卷第11期 中国有色金属学报 2010年11月 ～，01．20No．1l ofNonferrousMetals TheChineseJournal Nov．2010 1．2260．09 文章编号：1004．0609(2010)1 298．15 邱文顺1，李运姣1，赵中伟1，霍广生1，习小明2，陈盼盼1 (1．中南大学冶金科学与工程学院，长沙410083：2．长沙矿冶研究院，长沙410012) 绘制在298．15 的可行性。 关键词：Li-Ti-H20系；Li4Ti5012；热力学；合成 中图分类号：TM912．9 文献标志码：A of at298．15Kand Li—Ti—H20 纩-pHdiagram system of Li4Ti5012 synthesis Wen．shunl，LI Xiao．min92，CHEN QIc Yun-jia01，ZHAOZhong-weil，HUOGuang-shen91，XI Pan．panl of Scienceand South 41 (1．School MetallurgicalEngineering，CentralUniversity,Changsha0083，China； ResearchInstitute and 2．Changsha ofMiningMetallurgy,Changsha 410012，China) Abstract：Thestandardfree theformationof and were Gibbs of estimated energies Li2Ti307，Li4Ti5012Li4Ti04 using modeland linear of and atdifferent rule．The旷一pHdiagramsTi—H20 two—parametercongeneric Li-Ti-H20systems concentrationsweredrawnat298．15K．Theresultsshowthat hasa stableareainawide Li4Ti5012thermodynamically between4．1and13．7in solution．Thisindicatesa forthe of pHrange aqueous greatpossibilitysynthesisLi4Ti5012．11le froman solutionforced at