Sol-gel法制备Er3+掺杂Yb2Ti2O7薄膜及其上转换发光特性研究.pdf

· · sol—gel法制备Ers十掺杂Yb：Ti20，薄膜及其上转换发光特性研究／刘晓兰等 171 刘晓兰，吴金磊，何洋洋，曹保胜 (大连民族学院物理与材料工程学院，大连116600) 摘要 膜。采用x射线衍射仪(XRD)和扫描电子显微镜(SEM)对薄膜的相结构和表面及截面形貌进行了表征，通过荧光 光谱仪检测了薄膜的上转换发光特性。结果表明：Er3+掺杂的YbzTiz07薄膜为单一面心立方Yb2Ti207相结构，薄 膜表面较光滑平整，颗粒尺寸约为80nin。976 的绿色、红色和红外上转换发光，分别对应于Er3+的2H11／2／4S3／2—4Il班、4 Yb2Tb07薄膜的绿色和红色上转换发光均为双光子吸收过程。Er”掺杂YbzTiz0，薄膜和粉末的上转换发光光谱 还出现了绿色和红色上转换发光强度的变化。 关键词 Er3一掺杂Yb2Ti207 薄膜溶胶一凝胶法上转换发光 中图分类号：0484；0469；0433文献标识码：A Researchon and LuminescenceofEr3+ Sol—gelSynthesisUpconversion Films Yb2Ti207 Doped LIUXiaolan，WUinlei，HE J Baosheng Yangyang，CAO andMaterials Nationalities 116600) (Schoolof University，Dalian Physics Engineering，Dalian filmswere on siliconsubstrates Abstract5 Yb2 07 bysol—gel mol％Era+dopedTi2 depositedsinglecrystal methodand structureandthesurfaceandcrosssection ofthefilms spin-coatingtechnique．Thecrystal morphology election were diffraction(XRD)and investigatedbyX-ray scanning luminescenceofthefilmsweremeasuredfluorescence resultsindicatedthatEd+ properties by spectrometer．The filmswere of face-centeredcubic ofYb2 07，thefilms