ZnxCd1-xSTiO2异质结复合纤维的制备及其光催化性能.pdf

化 工 进 展 2013 年第 32 卷第 4 期 CHEMICAL INDUSTRY AND ENGINEERING PROGRESS ·853 · 研究开发 聚烯烃包覆石蜡相变材料的结构和初步热性能 苏磊静，丁雪佳，雷晓慧，何金迎，王林生，李熙然 （北京化工大学北京市新型高分子材料制备与加工重点实验室，北京 100029 ） 摘 要：分别以低密度聚乙烯（LDPE ）和乙烯-辛烯共聚物（POE ）为包覆材料，以石蜡为相变材料，制备了定 形相变材料，采用 SEM 、DSC 和流变性能对其进行分析表征。SEM 电镜显示了两种不同的表面形貌；DSC 测 试表明石蜡加入量越多，潜热越大，POE/石蜡体系的潜热高于 LDPE/石蜡体系；流变性能研究表明，石蜡的加 入在固态时提高了基体的储能模量，对于LDPE/石蜡体系，LDPE 为连续相；对于POE/石蜡体系，由于POE 和 石蜡熔融温度非常接近，分辨不出谁是连续相谁是分散相。 关键词：相变；聚烯烃；DSC；流变性能 中图分类号：TU 5 文献标志码：A 文章编号： 1000 –6613 （2013 ）04 –0853 –04 DOI ：10.3969/j.issn.1000-6613.2013.04.022 Structure and thermal properties of phase change materials based on polyolefin cladded paraffin wax blends SU Leijing ，DING Xuejia ，LEI Xiaohui ，HE Jinying ，WANG Linsheng ，LI Xiran （Beijing Key Laboratory of Preparation and Processing of Novel Polymer Materials，Beijing University of Chemical Technology ，Beijing 100029，China ） Abstract：Form-stable phase change materials were prepared by taking low density polyethylene (LDPE) and ethylene/octene copolymer (POE) as the cladding material and paraffin wax as phase change material respectively. SEM ，DSC and rheological curve were used to analyze and characterize the blends. SEM showed completely different morphology for the two systems. DSC indicated that the more the paraffin wax ，the greater the latent heat. The latent heat of POE/paraffin wax blend was greater than that of LDPE/paraffin wax blend. Rheological properties showed that paraffin wax improved the storage modulus of the matrix in its solid state. In LDPE/paraffin wax syst