添加TiO2组元的纳米级三元钛阳极涂层的组织形貌.pdf

第38卷 增刊 仓属学玫 V01．38Suppl． 2002年9月609—611页 ACTAMETALLURGICASINICA Sept．2002PP．609—611 添加Ti02组元的纳米级三元钛阳极涂层的组织形貌 王欣，) 唐电。) 周敬恩-’ 1)西安交通大学材料学院，西安710049 2)福州大学材料研究所，福州350002 摘 要 结构，添加Ti02细化晶粒的效果不显著．研究表明，涂层组成物主要为(Ru，Sn，Ti)02固溶体，Ti02含量增加，该固溶 体仍能稳定存在．退火温度升高后，发生单质Ru的析出，Ti02组元不能阻止涂层析出Ru单质．添加Ti02的涂层晶粒外观 成等轴状特征． 关键词 钛阳极，溶胶凝胶法，纳米涂层， TiQ 中图法分类号TGl74 文献标识码 A k EFFECTSoF oNTHE Ti02 ANDsoLIDPHAsEoF PHoLoGY ANoDE WANG U Xin¨，TANGDio护)，ZHOJing’enl) ofMaterialScienceand 710049 1)Department Engineering，Xi’anJiaotongUniversity,Xi’an forMaterials 350002 2)Institute Research，FuzhouUniversity,Fuzhou Correspondent：WANGXin，Tel：(029)2673261，E-mail：xinwx@263．net received2002-03-25 Manuscript withdifierentamountSof wereob— ABSTRACT coatedtitaniumanodes Ru02一Ti02--Sn02 Ti02 taineda and sizeoftheTi microstructure，morphologyparticle supported by sol—gelprocedure．The wasshownthatthe consisted wereexaminedmeansofXRD．DTAandTEM．It coatings by coatings ofasolid andits sizewaslessthan25am．WhentheamountofTi02 solution-(Ru，Sn，Ti)02crystal from11％to41％the ofthe sizewas wasstill changed change crystal very1ittle．The(Ru，sn，Ti)02 whentheamountof wasas as metallicrutheniumwasfoundwhenthe stable Ti09 high41％．The from450℃to600℃．Thewas