Chemical characteristics and source apportionment of PM10 during a brown haze episode in Harbin.pdfVIP

Particuology9 2011 32—38 。 comentsiistsavailableatSeienceDirect - -曩 -lolurinat b++mep+a ++wielmevierl~orn／Iocate／partiC 爱一 Chemica。characteristicsandsourc ofPM 】 hernlCalch andsourceaDDortionmentofP 1odduurrinngabrownhhaazzee ． 。 ． episodeinHarbin，China LikunHuang ，一，Chung—ShinYuan ，d ，GuangzhiW angbKunW angb 。 SchoolofFoodEngineering,HarbinUniversityofCommerce，Harbin150076,China SchoolofMunicipalandEnvironmentalEngineering,HarbinInstituteofTechnology．Harbin150090．China StateKeyLaboratoryofUrbanWaterResourcesandEnvironments，HarbinInstituteofTechnology，Harbin150090，China InstituteofEnvironmentalEngineering,NationalSunYot-senUniversiyt，Taiwan80424，China A R T IC L E IN F 0 A B S T R A C T Articlehistory： ThisstudyinvestigatesthecorrelationbetweenPM1oandmeteorologicalfactorssuchaswindspeed ， Received19January2010 atmosphericvisibility，dew point，relativehum idity，andambienttemperatureduringabrown haze Receivedinrevisedform 2July2010 episode．InordertoidentifythepotentialsourcesofPMloduringbrownhazeepisode respirablepar— Accepted16July2010 ． ticulatematter PM10 wascollectedduringbothnon—hazedaysandhazedaysandfurtheranalyzed f0rmetallicelements，ionicspecies。andcarbonaceouscontents．Amongthem ．ionicspeciescontributed Keywords 45—64％toPMlO，whilemetallicelementscontributed7—21％toPM10whichwassmallerthantheother PM lo Chemicalanalysis chemicalconstituents．TheaverageOC／ECratio 42 inhazedayswasaboutthreetimesoftheaverage Mete0r010 ca1factors OQECratio 14 innon—hazedays．Byusingchemicalmassbalance CMB receptormodel。themajor CMBreceptormodel sourceswereapportioned，includingtraffics，incinerators，coaIcombustion，steelindustry．petrochemical Sourceapportionment industry，andsecondary aerosols．etc．ThecontributiontoPM10c0ncentrati0nOfeachsourcewascalcu一 1atedforallthesamplescollected．TheresultsshowedthatcoalcombustionwasthemajorsourceofPM1n innon—hazedaysandsecondaryaerosolswerethemajorsourceinhazedays．ofllowedbypetrochemical jndustry．jncinerators．andtraffics．whileothersour