Coal pyrolysis in a fluidized bed reactor simulating the process conditions of coal.pdfVIP

Journal of Analytical and Applied Pyrolysis 91 (2011) 241–250 Contents lists available at ScienceDirect Journal of Analytical and Applied Pyrolysis j o u rn al h omepage: w w w. elsev /locate/jaap Coal pyrolysis in a fluidized bed reactor simulating the process conditions of coal topping in CFB boiler Xiaofang Zhang, Li Dong, Juwei Zhang, Yajun Tian, Guangwen Xu ∗ State Key Laboratory of Multi-Phase Complex System, Institute of Process Engineering, Chinese Academy of Sciences, ZhongGuanCun Bei’ertiao 1, Haidian District, Beijing 100080, China a r t i c l e i n f o a b s t r a c t Article history: Simulating the conditions of pyrolytic topping in a fluidized bed reactor integrated into a CFB boiler, the Received 14 September 2010 study was devoted to the reaction fundamentals of coal pyrolysis in terms of the production character- Accepted 18 February 2011 istics of pyrolysis oil in fluidized bed reactors, including pyrolysis oil yield, required reaction time and Available online 26 February 2011 the chemical species presented in the pyrolysis oil. The results demonstrated that the maximal pyrolysis oil yield occurred on conditions of 873 K, with a reaction time of 3 min and in a reaction atmosphere gas Keywords: simulating the composition of pyrolysis gas. Adding H2 and CO2 into the reaction atmosphere decreased Coal topping the pyrolysis oil yield, while the oil yield increased with increasing the CO and C