化学发光法测定卷烟主流烟气中的氮氧化物.pdfVIP

( ) 烟草科技/ 烟草化学 Tobacco Science Technology/ Tobacco Chemistry 2005 年第 1 期 总第 210 期 化学发光法测定卷烟主流烟气中的氮氧化物 朱立军 , 戴 　亚 , 谭兰兰 , 邓发达 , 彭 　忠 , 吕杰超 (重庆烟草工业公司技术中心 ,重庆市南岸区南坪东路 2 号 　400060) 关键词 :化学发光法 ;氮氧化物 ;卷烟 ;主流烟气 摘要 :探讨了一种用化学发光法测定卷烟主流烟气中NOx 的方法 , 即将每 口新鲜主流烟气经剑桥 滤片过滤后引入到一个减压的混合室 ,经充分混合后 ,用氮氧化物分析仪根据化学发光原理测定卷烟主 流烟气中氮氧化物 。该方法的 CV 5 % , 回收率 98 % ,并用外标法定量测定了 6 种牌号卷烟主流烟气 中的氮氧化物 。该方法快速 、重复性好 、回收率高 ,适用于卷烟烟气中的氮氧化物的分析 。 ( ) 中图分类号 :TS411. 2 　文献标识码 :B 　文章编号 :1002 - 0861 2005 01 - 0033 - 05 Determination of NOx in Mainstream Smoke by Chemiluminescence ZHU LIJUN , DAI YA , TAN LANLAN , DENG FADA , PENG ZHONG, and LüJ IECHAO Technology Center of Chongqing Tobacco Industrial Co. , Ltd. ,Chongqing 400060 , China Keywords : Chemiluminescence ; Nitrogen oxides ; Cigarette ; Mainstream smoke Abstract : A chemiluminescent method for determining nitrogen oxides (NOx) in mainstream cigarette smoke was deliberated. The gas phase of mainstream smoke filtered by Cambridge pad was directed into an evacuated mixing chamber puff by puff , and then NO was determined by an NO analyzer according to the chemiluminescent theory. x x The CV of this method was below 5 % and the recovery of NO was over 98 %. Two components , nitrogen monoxide x (NO) and nitrogen dioxide (NO2) , in mainstream smoke of six brands of cigarettes were determined with an exter nal standard method. It was concluded that this method had high repeatabilit