木质素两性表面活性剂的合成及表面物化性能.pdfVIP

278 精 细 化 工 V ol. 27, N o. 8 2 0 1 0 8 FINE CH EM ICAL S A ug. 2 0 1 0 * 徐永建, 付旭东 ( , 71002 1) : , ( 2, 3 ) ( DMA C) , ( SL ) , LA S : , n( SL ) !n( DM AC) = 1!11, 3 h, pH = 12, 55 ∀ , 225% UV, CM C 3 g / L, 2111 mN /m, HLB 10 CMC : ; ; : TQ 423. 3 : A : 1003- 5214 ( 20 10) 08- 0765- 05 Synthesis of L ignin Amphoteric Surfactant andM easurem ents of Their Physicchem ical P roperties * XU Y ongj an, FU X udong (K ey Laboratory of A ux iliary Chem istry and Technology in L ight Industry, M inistry of Education, Shaanx i Uni ersity of S cience Technology, X i#an 71002 1, Shaanx ,i Ch ina) Ab stract ( 2, 3Epoxypropy l) d m ethy lamm on um chlor de ( DMA C ) w as synthes zed w th N, N dm ethy l dodecy lam ne and ep ch lo rohy as raw m ater als n th s art cle. T hen the LA S ( l gn n am photer c surfactan t) w as prepared by the DMAC w th SL ( sulphonated l gn n ). T hrough the orthogonal experm ent, the optm a l preparat on cond t on w as nvest gated: u s ng acetone as the solvent, n ( SL) !n ( DMA C) w as 1!11, react on t m e w as 3 h, react on tem perature 55 ∀ , pH va lue w as 12. The n trogen conten t of LA S reached 225% . T he structure of the product was character zed by FT IR spectrum, UV and e lem entary ana lys s. T he surface act v t es o f the product w ere m easured: cr t ca l