聚氨酯胶粘剂的热分解动力学研究.pdfVIP

物理化学学报(Wuli Huaxue Xuebao) 1622 A cta Phys. Chim. Sin., 2007, 23(10) 1622-1626 October [Note] 聚氨酯胶粘剂的热分解动力学 爱玲 熊金平* 左 禹 王成忠 (北京化工大学材料科学与工程学院, 北京 100029) 摘要： 采用热分析技术考察了通用型聚氨酯胶粘剂在空气中的热解过程, 并通过TG 方法和动力学方法研究 了各步反应的活化能E 、指前因子A 等动力学参数. 通过等失重转化率法校验了两种方法所获得的E 和A 值. 结 果表明, 聚氨酯胶粘剂有三个主要降解阶段, 第一降解阶段的活化能为144.31-148.35 kJ ·mol-1, 第二个降解阶段 的活化能为196.96-204.26 kJ ·mol-1, 第三个降解阶段的活化能为202.97-205.27 kJ ·mol-1; 热降解过程为一级反 应, 随着失重百分率的增大, 热分解反应活化能增大. 此外, 聚氨酯胶粘剂具有较高的热稳定性, 预测其在35 的空气中失重5豫时的热老化寿命为10 年. 关键词: 聚氨酯胶粘剂; 热分解; 寿命预测 ： 中图分类号 O648 Thermal Decomposition Kinetics of Polyurethane Adhesive LI Ai鄄Ling XIONG Jin鄄Ping* ZUO Yu WANG Cheng鄄Zhong (School of Materials Science and Engineering, Beiji ng University of Chemical Technology, Beij ing 100029, P. R. China) Abstract: The thermal behavior of polyurethane adhesive in air atmosphere was investigated by thermogravimetry (TG) and derivative thermogravimetry (DTG) . The kinetic parameters were evaluated by TG method and dynamic method, and the isoconversional method was employed to verify the values. The results showed that there were three main decomposition stages in the DTG curves. The apparent activation energy values determined using the TG method were 144.31-148.35 kJ ·mol-1 for the first stage of decomposition, 196.96-204.26 kJ ·mol-1 for the second stage, and 202.97-205.27 kJ ·mol-1 for the third stage. The non鄄isothermal degradation was found to be first order reaction, and the activation energy increased with the increase