一种新型铝空气电池用铝合金阳极材料的研究.pdfVIP

Material Sciences 材料科学, 2012, 2, 52-57 doi:10.4236/ms.2012.21009 Published Online January 2012 (/journal/ms) Study on a New Kind of Al Alloy Anode Material for Aluminum-Air Battery Xiaoxiang Li, Zhengqing Ma, Zhaoyang Teng School of Materials Science and Engineering, Central South University, Changsha Email: **************** Received: Sep. 30th, 2011; revised: Oct. 21st, 2011; accepted: Oct. 26th, 2011. Abstract: A new kind of Al alloy anode material for aluminum-air battery was developed by orthogonal design, and the effect of additive elements on hydrogen evolution rate and electrochemical properties in 4 mol/L NaOH + 15 g/L Na SnO solution was studied. Then the best performance ratios of aluminum alloy anode material composition can be 2 3 finally got. The self-corrosion rate of Al alloy anode was studied by methods of recovering H2 gas and discharging wa- ter and the electrochemical properties were tested by LK3200 electrochemical workstation. The results show that the greatest impact on the hydrogen evolution rate of aluminum alloy anode material at 50˚C is Pb, followed by Sn, Ga; at the same time, the greatest impact on the stable potential at 50˚C and 200 mA/cm2 is Sn, followed by Pb, Ga. After con- sidering and verifying the stable potential and hydrogen evolution rate of aluminum alloy anode, we can obtain the op- timal combination: Al-0.2Sn-0.02Ga-0.4Pb. Keywords: Aluminum Alloy Anode; Orthogonal Design Method; Hydrogen Evolution Rate; Stable Potential 一种新型铝空气电池用铝合金阳极材料的研究 李晓翔，马正青，滕昭阳 中南大学材料科学与工程学院，长沙 Email: *********** 收稿日期：2011 年 9 月 30 日；修回日期：2011 年 10 月 2