多环芳烃(PAHs)在砂质土壤中的吸附行为.pdfVIP

维普资讯 农业环境科学学报 2005，24(1)：69—73 JournalofAgro—EnvironmentScience 多环芳烃(PAHs)在砂质土壤中的吸附行为 陈 静，王学军，胡俊栋，陶 澍，刘文新 (北京大学环境学院，地表过程分析与模拟教育部重点实验室，北京 100871) 摘 要：采用室内试验方法，研究了多环芳烃(PAHs)在砂质土壤中的吸附行为。结果表明，两阶段吸附模型可较好地模 拟PAHs在砂土中的动力吸附过程：快速的线性吸附阶段和慢速吸附阶段。慢速吸附阶段可用乘幂方程拟合，幂指数反 映了吸附速率的大小。多环芳烃在砂土中的吸附行为不仅与砂土的性质有关 (例如有机碳含量)，而且受 PAHs物化性质 (辛醇 ／水吸附系数、分子连接指数、分子长度、水溶解度)的影响。与低环PAHs相比，高环PAHs较易吸附到砂土中，且 吸附量较大，可用土 一水吸附系数表示PAHs的吸附行为。 关键词：多环芳烃；砂质土壤；吸附 中图分类号：xl31．3 文献标识码：A 文章编号：1672—2043(2005)01—0069—05 AdsorptionofPolycyclicAromaticHydrocarbons(PAHs)inSandSoils CHENJing，WANGXue—jna，HUJun—dong，TAOShu， LIUWen—xin (CollegeofEnvironmentSciences，KeyLaboratoryforSurfaceProcesses，Ministry ofEducation，PekingUniversity，Beijing lo0871．China) Abstract：AdSOrptionofPAHsinsandsoilswasstudiedinthisinvestigation．Theresultsshowedthattwo—phasemodelCallbeused todescribethesorptiondynamicofPAHsinthesoils．Thefirstphasewaslinearsorptionandthesorptionvelocitywasrapid，whilethe adsorptionspeedofPAHsinthesoilsmaybedescribedbysoprtioncoefficient．Thesecondphasewassimulatedbypowerequation andpowerexponentindicatedthesoprtionspeed．ThesoprtionofPAHswasnotonlyaffectedbysoilproperties(e．g．TOCcontent)， butalsoaffectedbyphysicalandchemicalstructures (e．g．octane—waterpartitioncoefficient，molecularconnectivityindex， molecularlength，solubility)oftheindividualPAHs．1ogKocvalueofPAHscalculatedbyisothermsoprtionexperimentWaspro- portiontooctane—waterpartitioncoefficientandmolecularconnectivityindex，whileinverseproportiontosolubilityofPAHs．Th e capacitiesofPAHssoprtionincreasedwiththeincreaseofoctane—waterpartitioncoefficientandmolecularconnectivityindex，while decreasedwiththeincreaseofsolubilityofPAHs．However，thereWasnoamarkedrelativitybetweenlogKoevaluesofPAHsandtheir molecularlength．ThesoilsampleswithhigherTOCcontentshadstrongersoprtioncapability，andPAHswiht bigerringhadhisher soprtionamountandspeedinsoilcomparedtolowrin