一种巯基胺型羧酸螯合树脂的制备及其吸附性能.pdfVIP

274 精 细 化 工 Vo.l 27, No. 4 2 0 1 0 4 FINE CHEM ICALS Apr. 2 0 1 0 * 张光华, 刘林涛 , 胡晓虹, 李 雯, 朱雪丹 ( , 71002 1) : , ( PA ) PA , ( PA C) , ( FT IR ) 2+ 2+ PAC Cu , pH Cu 2+ , , 25 mL 10 mmol/L, PAC Cu 040 /mmol Cu2+ , 150 m in, pH 6~ 10, 253 2+ mm ol/ 947% PAC Cu Lan m iur Freundlich : ; ; Cu2+ ; ; ; : X703 : A : 1003- 5214( 2010) 04- 0400- 05 Preparation of aM ercaptoam inocarboxylic Acid Chelating Resins and St dy on TheirAdsorption Properties * ZHANG Guan hua, LIU L intao , HU X iaohon , LIW en, ZHU Xuedan (Key Laboratory of Auxiliary Chemistry Technologyf or Chem ical Industry,M inistry of Education, Shaanxi niversity of Science Technology,X ian 71002 1, Shaanx,i China) Abstract:M ercaptoam ino( PA ) resinw as prepared by the crosslinked reaction of ch loromethylthiirane w ith polyethylene polyam ine. Then the PA resin reacted w ith chloroacetic acid to ive m ercapto am inocarboxylic acid( PAC) chelatin resins. The chem ical structure of resins w as characterized by FT IR. The adsorption performance of PAC chelatin resins to smi ulated electrop latin w astew ater 2+ contain in Cu w as investi ated. The influences of quantity of resins, adsorption tmi e and pH value on