季铵化NO羧甲基壳聚糖的制备及其合成条件优化.pdfVIP

11 ! 667 ! N, O 1 * 2 , ( 1. , 210012; 2. , 224003) : 以N, O羧甲基化度为85. 6% 的羧甲基壳聚糖( CMCT S) 为原料, w= 0. 40 的NaOH 水溶 液为催化剂, 3氯2羟丙基三甲氯化铵( CT A) 为接枝改性剂, 在异丙醇介 中制备了具有良好水 + 溶性的两性壳聚糖季铵化N, O羧甲基壳聚糖; 分别以产物对模拟废水中的Cd 和Cr( ) 的絮凝 1 去除率为基准对两性壳聚糖的合成条件进行了优化; 用 IR 和 H NM R 对产物的结构进行了表征 研究结果表明产物Cr( ) 的去除率更适宜作为合成条件的优化基准, 且对应的优化条件为: 季铵 化反应时间为10. 0 , 反应温度为60. 0 , mNaOH / mCM- CTS = 0. 50, mCTA / mCM- CTS = 1. 5; 在此条件 2+ 下合成产物对Cr( ) 的最大絮凝去除率为93. 16% , 对Cd 的最大絮凝去除率98. 52% :N, O羧甲基壳聚糖; 3氯2羟丙基三甲基氯化铵; 接枝改性; 季铵化N, O羧甲基壳聚糖; 正交实验 : O 636. 1 : A : 2008) 1166704 Preparation of Quaternized N, OCarboxymet yl C itosan and Opt imization of t e Synt etic Conditions YANG Wei, CAI Z aos eng (1. Dep artment of Forensic Science, J iangsu Police Institute, J iangsu N anj ing 210012 , hina; 2. Dep artment of hemical and Biological Engineer ing, Yancheng I nstiute of Technology , J iangsu Yancheng 224003, hina) Abstract : A amp oteric c itosan w it a ig er solubility in w ater w as prepared w it 2propanol as solvent, w = 0. 40 NaOH aqueous solution as catalyst, 3c loro2 ydroxypropyl trimet lyammonium c loride ( CTA) as grafting agent and N, Ocarboxymet ylc itosan( CMCT S) w it carboxymet yl degree of 85. 6% as starting material. T e synt etic conditions were optimized according to ort ogonal experimens t at 2+