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Abstr3ct
Abstract
LingW酾g(Physic“Chemis嘞
DirectedProf
by XiuyazlWaIlg
Pr0£XuemingY锄g
强isdisse砖at她is of铆o fl糕t is搬edet西led
composedpafts.弧epart
stud主esofunimokcularr。ac吐onS
dissociation abinitio瓜RKM
by theory;the
second is theconStructionof fbr
part six-dimensionalPES fou卜atom
reaction method.
photodissociationbyinte巾olated
ThefirstI它action studiedabjnit王。庄U朝(Mis
system by O(’D)十NH3
collision isshowntooccur inse《on
react{on,which mainlythrou曲the
mecb蕊sm the
involVinglon铲liVedchemic雒ly
T圭l呈s int。矾ediatc dissocia聋estov越ous viasome
ene孪zod quickly products
cr嫩caI calcula如d ratiosofvarious
con是guratiOns.Thebranching
of
productsNH20H+呲inagrcemcntⅥdtll
good recenny
Values.T11isreactioncanalso add“ion/abstractionmech姐ism
proceed也rou曲me
onthefirstexcited—s诅te accountsformefonⅣard
PES,whichpaniaIly scattering
oftheOH
productsObseNed讯experiment.
弧eCH筘inte潍edlatc
畦地ndissoci磊姥viafotlr
productchannels,including
RRKM is to rateconstantsand
CHF,andH+CH2Ftheoryapplied
compute
ratiosofmefour channelsatvarious and
branchiIlg pmduct colIision。ne礓i
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