一种制备高长径比金纳米棒新方法.pdfVIP

2011 年第69 卷 化 学 学 报 Vol. 69, 2011 第14 期, 1617～1621 ACTA CHIMICA SINICA No. 14, 1617～1621 ·研究论文· 一种制备高长径比金纳米棒的新方法 高 倩 a,b 钱 勇a,b 夏 炎 a 蒋彩云 a 钱卫平*,a (a 东南大学生物科学与医学工程学院 生物电子学国家重点实验室 南京 210096) (b 东南大学化学化工学院 南京 211189) 摘要 报道了一种制备高长径比金纳米棒的新方法. 在25 ℃条件下, 采用种子介导生长法, 通过优化表面活性剂十六 烷基三甲基溴化铵(CTAB)的浓度, 制备了长度(200 ±18.62) nm, 长径比大于10 的金纳米棒, 并讨论了金纳米棒的形成 机制. 结果表明, 金纳米棒的长径比和纵向吸收波长与CTAB 的浓度有关. 此外, 通过提高反应液的离子强度, 利用制 备的金纳米棒与球形颗粒不同的静电作用将金纳米棒分离纯化. 运用透射电子显微镜(TEM)和扫描电子显微镜(SEM) 对金纳米棒的表面形貌进行表征. 关键词 金纳米棒; 十六烷基三甲基溴化铵; 离子强度; 高长径比 A Novel Method to Prepare High-aspect Ratio Gold Nanorods Gao, Qiana,b Qian, Yonga,b Xia, Yana Jiang, Caiyuna Qian, Weiping*,a a ( State Key Laboratory of Bioelectronics, School of Biological Science and Medical Engineering, Southeast University, Nanjing 210096) (b School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189) Abstract A novel approach to high-aspect ratio gold nanorods has been presented. The gold nanorods as long as (200 ±18.62) nm with aspect ratio of above 10 were prepared with optimizing the concentration of surfactant cetyltrimethylammonium bromide (CTAB) by seed-mediated growth method at 25 ℃. Mechanism for gold nanorods formation is discussed. It is shown that the aspect ratio and longitudinal surface plasmon resonance (SPR) can be correlated with the concentration of CTAB. Moreover, by simply enhancing the ion strength of the reaction solution, the as-prepared gold nanorods can be purified