Effect of cooling rate on the solidification of Cu58Co42.pdfVIP

Materials Science and Engineering A 449–451 (2007) 644–648 Effect of cooling rate on the solidification of Cu58Co42 S. Curiotto a,b,c,∗, N.H. Pryds a , E. Johnson a,b , L. Battezzati c a Materials Research Department, AFM 228, Risø National Laboratory, Frederiksborgvej 399, DK-4000 Roskilde, Denmark b Niels Bohr Institute, Nanoscience Centre, University of Copenhagen, Copenhagen, Denmark c Dipartimento di Chimica IFM, Centro di Eccellenza NIS, Universit`a di Torino, Via P. Giuria 9, 10125 Torino, Italy Received 21 August 2005; received in revised form 14 December 2005; accepted 24 February 2006 Abstract This paper deals with Co42 Cu58 (at.%) alloy processed to obtain a cooling rate gradient during solidification. The Co–Cu system displays a metastable miscibility gap in the liquid state. Undercooling of the melt beyond a certain limit results in liquid separation and formation of droplets of the minority phase in a matrix of the dominant phase. The material was melted and cast in a wedge shaped copper mould to obtain a gradient of cooling rates. The cooling history of the alloy during the solidification was monitored by insertion of thermocouples at different positions in the mould. During cooling, the melt separated into droplets of Co-rich and Cu-rich phases. The Co-rich droplets are mainly coagulated along the major axis of the samples and an explanation of this segregation mechanism is proposed. The distribution of the size of the Co-rich particles was measured in various areas along the sample and correlated to the cooling rate. © 2006 Elsevier B.V. All rights reserved.