Effectsofcrystal省略7Eu2phosphors杨鹏辉.pdfVIP

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Effectsofcrystal省略7Eu2phosphors杨鹏辉.pdf

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Effectsofcrystal省略7Eu2phosphors杨鹏辉.pdf

JOURNAL OF RARE EARTHS, Vol. 30, No. 12, Dec. 2012, P. 1208 2+ Effects of crystal field on photoluminescence properties of Ca Al SiO :Eu 2 2 7 phosphors 1 1,2 1 1 1,2 YANG Penghui (杨鹏辉) , YU Xue (余雪) ,YU Hongling (余红玲) , JIANG Tingming (姜庭明) , ZHOU Dacheng (周大成) , QIU Jianbei (邱建备)1,2 (1. College of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650093, China; 2. Key Laboratory of Advanced Materials of Yunnan Province, College of Materials Science and Engineering, Kuming University of Science and Technology, Kunming 650093, China) Received 20 July 2012; revised 24 September 2012 2+ Abstract: A series of single-phased Ca Al SiO :Eu phosphors were synthesized by the solid-state reaction. Their structure and photolumi- 2 2 7 nescence properties were investigated by the X-ray powder diffraction (XRD) and excitation and emission spectra in detail. The emission spectra of Ca 2+ Al SiO :Eu phosphors consisted of blue and green band located at 419 and 542 nm, respectively. The relative intensities of the 2 2 7 blue and green emission changed with Eu2+ concentration and were sensitive to the excitation wavelength. The unique photoluminescence property originated from the 4f7 6